Matching Items (10)
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- All Subjects: urban planning
- Creators: School of Sustainability
- Creators: Anderson, Anthony David
- Member of: Barrett, The Honors College Thesis/Creative Project Collection
- Resource Type: Text
Description
Within recent years, metal-organic frameworks, or MOF’s, have gained a lot of attention in the materials research community. These micro-porous materials are constructed of a metal oxide core and organic linkers, and have a wide-variety of applications due to their extensive material characteristic possibilities. The focus of this study is the MOF-5 material, specifically its chemical stability in air. The MOF-5 material has a large pore size of 8 Å, and aperture sizes of 15 and 12 Å. The pore size, pore functionality, and physically stable structure makes MOF-5 a desirable material. MOF-5 holds applications in gas/liquid separation, catalysis, and gas storage. The main problem with the MOF-5 material, however, is its instability in atmospheric air. This inherent instability is due to the water in air binding to the zinc-oxide core, effectively changing the material and its structure. Because of this material weakness, the MOF-5 material is difficult to be utilized in industrial applications. Through the research efforts proposed by this study, the stability of the MOF-5 powder and membrane were studied. MOF-5 powder and a MOF-5 membrane were synthesized and characterized using XRD analysis. In an attempt to improve the stability of MOF-5 in air, methyl groups were added to the organic linker in order to hinder the interaction of water with the Zn4O core. This was done by replacing the terepthalic acid organic linker with 2,5-dimethyl terephthalic acid in the powder and membrane synthesis steps. The methyl-modified MOF-5 powder was found to be stable after several days of exposure to air while the MOF-5 powder exhibited significant crystalline change. The methyl-modified membrane was found to be unstable when synthesized using the same procedure as the MOF-5 membrane.
ContributorsAnderson, Anthony David (Author) / Lin, Jerry Y.S. (Thesis director) / Ibrahim, Amr (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
This paper explores women and bicycling, with the focus of looking at how to get more women onto the bicycle in Tempe, Arizona. The main areas of interest for this study are improvements to bicycling infrastructure and an increase in the safety and the perception of safety of women cyclists in the Tempe area. In order to explore this topic, an online survey of 75 Arizona State students was conducted. From the results women were primarily concerned with their safety due to the condition of the overall infrastructure and the lack of bicycle related improvements. Research such as this that examines women and cycling is significant due to the current underrepresentation of women in the cycling community and has the potential to improve safety and increase bicycle ridership.
ContributorsStarr, Nicole (Author) / Kelley, Jason (Thesis director) / Golub, Aaron (Committee member) / Barrett, The Honors College (Contributor) / Herberger Institute for Design and the Arts (Contributor) / School of Sustainability (Contributor)
Created2014-12
Description
Defines the concept of the arcology as conceived by architect Paolo Soleri. Arcology combines "architecture" and "ecology" and explores a visionary notion of a self-contained urban community that has agricultural, commercial, and residential facilities under one roof. Two real-world examples of these projects are explored: Arcosanti, AZ and Masdar City, Abu Dhabi, UAE. Key aspects of the arcology that could be applied to an existing urban fabric are identified, such as urban design fostering social interaction, reduction of automobile dependency, and a development pattern that combats sprawl. Through interviews with local representatives, a holistic approach to applying arcology concepts to the Phoenix Metro Area is devised.
ContributorsSpencer, Sarah Anne (Author) / Manuel-Navarrete, David (Thesis director) / Salon, Deborah (Committee member) / Barrett, The Honors College (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor)
Created2015-05
Description
The goals of the styrene oxide adsorption experiments were to develop reliable isotherms of styrene oxide onto Dowex Optipore L-493 resin and onto mesoporous carbon adsorbents, in addition to determining the ideal conditions for styrene oxide production from E. coli. Adsorption is an effective means of separation used in industry to separate compounds, often organics from air and water. Styrene oxide adsorption runs without E. coli were conducted at concentrations ranging from 0.15 to 3.00 g/L with resin masses ranging from 0.1 to 0.5 g of Dowex Optipore L-493 and 0.5 to 0.75 g of mesoporous carbon adsorbent. Runs were conducted on a shake plate operating at 80 rpm for 24 hours at ambient temperature. Isotherms were developed from the results and then adsorption experiments with E. coli and L-493 were performed. Runs were conducted at glucose concentrations ranging from 20-40 g/L and resin masses of 0.100 g to 0.800 g. Samples were incubated for 72 hours and styrene oxide production was measured using an HPLC device. Specific loading values reached up to 0.356 g/g for runs without E. coli and nearly 0.003 g of styrene oxide was adsorbed by L-493 during runs with E. coli. Styrene oxide production was most effective at low resin masses and medium glucose concentrations when produced by E. coli.
ContributorsHsu, Joshua (Co-author) / Oremland, Zachary (Co-author) / Nielsen, David (Thesis director) / Staggs, Kyle (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / School of Sustainability (Contributor)
Created2014-05
Description
City planners often use bicycle friendly rating schemes as tools to guide them in their efforts to establish a bicycle community. However, the criteria and methodologies used vary from program to program and often do not encapsulate all of the necessary elements that comprise true bicycle friendliness. This report documents the important elements, strategies, and best practices that well-established Dutch, Danish, and German bike friendly cities exhibit to create a baseline standard for bicycle friendliness. Not all rating programs' criteria and methodologies align perfectly within this understanding of bicycle friendliness. City planners should use these programs as tools while keeping their limitations in consideration. The City of Tempe currently uses the League of American Bicyclists Bicycle Friendly Community program and BikeScore.com. By understanding the limitations associated with these programs, Tempe should move forward in their pursuit of bicycle friendliness by using multiple rating programs simultaneously and by looking at top-rated cities' strategies to enhance their infrastructure, network, urban form, and biking culture.
ContributorsTrombino, Frank Michael (Author) / Golub, Aaron (Thesis director) / Kelley, Jason (Committee member) / Barrett, The Honors College (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor)
Created2014-05
Description
Metal-organic frameworks (MOFs) are a new set of porous materials comprised of metals or metal clusters bonded together in a coordination system by organic linkers. They are becoming popular for gas separations due to their abilities to be tailored toward specific applications. Zirconium MOFs in particular are known for their high stability under standard temperature and pressure due to the strength of the Zirconium-Oxygen coordination bond. However, the acid modulator needed to ensure long range order of the product also prevents complete linker deprotonation. This leads to a powder product that cannot easily be incorporated into continuous MOF membranes. This study therefore implemented a new bi-phase synthesis technique with a deprotonating agent to achieve intergrowth in UiO-66 membranes. Crystal intergrowth will allow for effective gas separations and future permeation testing. During experimentation, successful intergrown UiO-66 membranes were synthesized and characterized. The degree of intergrowth and crystal orientations varied with changing deprotonating agent concentration, modulator concentration, and ligand:modulator ratios. Further studies will focus on achieving the same results on porous substrates.
ContributorsClose, Emily Charlotte (Author) / Mu, Bin (Thesis director) / Shan, Bohan (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
Description
There are unfortunately very few curricular guides that focus on community engagement within the higher education of landscape architecture. A Beginner’s Guide to Community Engagement in the Curriculum of Landscape Architecture and Urban Planning to Improve Social Justice and Sustainability helps resolve this issue and serves as a resource to students, educators, designers, and more. The guide centralizes a diverse collection of resources, guides students through learning materials, shares insight, and proposes potential community engagement methods. The booklet aims to help readers understand the importance of community engagement in design and shares different curricular approaches to introduce the work to students.
ContributorsNeeson, Margaret (Author) / Cheng, Chingwen (Thesis director) / Coseo, Paul (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / The Design School (Contributor)
Created2023-05
Description
This thesis explores the role and meaning of community in the community land trust (CLT) model, and uses a single embedded case study to examine the mission, organizational structure, and governance model of Newtown CDC, a CLT based in Phoenix, Arizona. The thesis seeks to answer the questions, “What does community participation and empowerment mean to Newtown CDC”, and “how does the organization satisfy the competing needs of community participation and affordable housing production?” Historical documents of Newtown CDC, interviews with CLT staff, board members, and national policy representatives, as well as a survey of current and former CLT residents, reveal the perceived meaning and role of community, its evolution, and successes and failures in engaging the community. The data finds that a change in political and cultural dynamics has contributed to more resources focused on developing affordable housing, and less focus on community engagement. CLTs have adapted to this change, and the role and execution of community engagement has also evolved.
ContributorsSubbaraman, Sree Manasvini (Author) / Ehlenz, Meagan (Thesis director) / Brewer, Stephanie (Committee member) / School of Geographical Sciences and Urban Planning (Contributor, Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
This research project is part of a larger study of green infrastructure in urban planning and sustainability initiatives in cities across the U.S. Within the past few decades, the topic of sustainability has been at the forefront of city planners’ minds as cities grow, there is new or redevelopment, and the threat of climate change and future climate variability increases. Green infrastructure is one increasingly popular urban sustainability strategy, which is widely promoted for its ability to provide multiple benefits. This multi-functionality translates into ecosystem services and possible disservices for a local community and the city as a whole. This research project examines 120 planning documents from 19 U.S. cities to examine whether the services cities say they expect green infrastructure to provide, or the rationale, match with the criteria used to determine where green infrastructure is sited. For this project, we ask: what are the rationales that cities provide for developing green infrastructure and what are the criteria cities are using to determine where to site it? We find that certain rationales, or benefits, are claimed without corresponding and specific siting criteria to substantiate how these benefits will be achieved, while other benefits, like those related to stormwater management, are prioritized over other potentially important benefits.
ContributorsColeman, Emma Ciara (Author) / Meerow, Sara (Thesis director) / Hoover, Fushcia-Ann (Committee member) / School of Molecular Sciences (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2020-12
Description
In urban planning and design, creating emotional bonds, known as place identity, between people and their surroundings is paramount to improving the well-being of those who reside there. However, determining how to alter the built environment in order to increase place identity is a difficult task to achieve. Walkability is a good mechanistic link between the built environment and place identity. Walkability is comprised of a suite of factors that take into consideration both the natural and built environment. This thesis aims to determine if walkability is positively correlated with place identity in an extreme climate such as Phoenix. To test this, ecosystem services and disservices are used as factors to measure overall walkability. We found that access to recreational opportunities, aesthetic features of the pathway, and safety were all significant predictors of place identity. This has positive implications for walkable infrastructure to be strengthened in desert cities.
ContributorsSiefert, Janelle (Author) / Larson, Kelli (Thesis director) / Kelley, Jason (Committee member) / Barrett, The Honors College (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor) / Watts College of Public Service & Community Solut (Contributor)
Created2022-05