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Description
It has been identified in the literature that there exists a "spatial mismatch" between geographical concentrations of lower-income or minority people who have relatively lower rates of car ownership, lower skills or educational attainment and who mainly rely on public transit for their travel, and low-skilled jobs for which they

It has been identified in the literature that there exists a "spatial mismatch" between geographical concentrations of lower-income or minority people who have relatively lower rates of car ownership, lower skills or educational attainment and who mainly rely on public transit for their travel, and low-skilled jobs for which they more easily qualify. Given this situation, various types of transportation projects have been constructed to improve public transit services and, alongside other goals, improve the connection between low-skilled workers and jobs. As indicators of performance, measures of job accessibility are commonly used in to gauge how such improvements have facilitated job access. Following this approach, this study investigates the impact of the Phoenix Metro Light Rail on job accessibility for the transit users, by calculating job accessibility before and after the opening of the system. Moreover, it also investigates the demographic profile of those who have benefited from improvements in job accessibility----both by income and by ethnicity. Job accessibility is measured using the cumulative opportunity approach which quantifies the job accessibility within different travel time limits, such as 30 and 45 minutes. ArcGIS is used for data processing and results visualization. Results show that the Phoenix light rail has improved job accessibility of the traffic analysis zones that are along the light rail line and Hispanic and lower-income groups have benefited more than their counterparts.
ContributorsLiu, Liyuan (Author) / Golub, Aaron (Thesis advisor) / Wentz, Elizabeth (Committee member) / Kuby, Michael (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Increasing concentrations of carbon dioxide in the atmosphere will inevitably lead to long-term changes in climate that can have serious consequences. Controlling anthropogenic emission of carbon dioxide into the atmosphere, however, represents a significant technological challenge. Various chemical approaches have been suggested, perhaps the most promising of these is based

Increasing concentrations of carbon dioxide in the atmosphere will inevitably lead to long-term changes in climate that can have serious consequences. Controlling anthropogenic emission of carbon dioxide into the atmosphere, however, represents a significant technological challenge. Various chemical approaches have been suggested, perhaps the most promising of these is based on electrochemical trapping of carbon dioxide using pyridine and derivatives. Optimization of this process requires a detailed understanding of the mechanisms of the reactions of reduced pyridines with carbon dioxide, which are not currently well known. This thesis describes a detailed mechanistic study of the nucleophilic and Bronsted basic properties of the radical anion of bipyridine as a model pyridine derivative, formed by one-electron reduction, with particular emphasis on the reactions with carbon dioxide. A time-resolved spectroscopic method was used to characterize the key intermediates and determine the kinetics of the reactions of the radical anion and its protonated radical form. Using a pulsed nanosecond laser, the bipyridine radical anion could be generated in-situ in less than 100 ns, which allows fast reactions to be monitored in real time. The bipyridine radical anion was found to be a very powerful one-electron donor, Bronsted base and nucleophile. It reacts by addition to the C=O bonds of ketones with a bimolecular rate constant around 1* 107 M-1 s-1. These are among the fastest nucleophilic additions that have been reported in literature. Temperature dependence studies demonstrate very low activation energies and large Arrhenius pre-exponential parameters, consistent with very high reactivity. The kinetics of E2 elimination, where the radical anion acts as a base, and SN2 substitution, where the radical anion acts as a nucleophile, are also characterized by large bimolecular rate constants in the range ca. 106 - 107 M-1 s-1. The pKa of the bipyridine radical anion was measured using a kinetic method and analysis of the data using a Marcus theory model for proton transfer. The bipyridine radical anion is found to have a pKa of 40±5 in DMSO. The reorganization energy for the proton transfer reaction was found to be 70±5 kJ/mol. The bipyridine radical anion was found to react very rapidly with carbon dioxide, with a bimolecular rate constant of 1* 108 M-1 s-1 and a small activation energy, whereas the protonated radical reacted with carbon dioxide with a rate constant that was too small to measure. The kinetic and thermodynamic data obtained in this work can be used to understand the mechanisms of the reactions of pyridines with carbon dioxide under reducing conditions.
ContributorsRanjan, Rajeev (Author) / Gould, Ian R (Thesis advisor) / Buttry, Daniel A (Thesis advisor) / Yarger, Jeff (Committee member) / Seo, Dong-Kyun (Committee member) / Arizona State University (Publisher)
Created2015
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Description
The development of microsimulation approaches to urban systems modeling has occurred largely in three parallel streams of research, namely, land use, travel demand and traffic assignment. However, there are important dependencies and inter-relationships between the model systems which need to be accounted to accurately and comprehensively model the urban system.

The development of microsimulation approaches to urban systems modeling has occurred largely in three parallel streams of research, namely, land use, travel demand and traffic assignment. However, there are important dependencies and inter-relationships between the model systems which need to be accounted to accurately and comprehensively model the urban system. Location choices affect household activity-travel behavior, household activity-travel behavior affects network level of service (performance), and network level of service, in turn, affects land use and activity-travel behavior. The development of conceptual designs and operational frameworks that represent such complex inter-relationships in a consistent fashion across behavioral units, geographical entities, and temporal scales has proven to be a formidable challenge. In this research, an integrated microsimulation modeling framework called SimTRAVEL (Simulator of Transport, Routes, Activities, Vehicles, Emissions, and Land) that integrates the component model systems in a behaviorally consistent fashion, is presented. The model system is designed such that the activity-travel behavior model and the dynamic traffic assignment model are able to communicate with one another along continuous time with a view to simulate emergent activity-travel patterns in response to dynamically changing network conditions. The dissertation describes the operational framework, presents the modeling methodologies, and offers an extensive discussion on the advantages that such a framework may provide for analyzing the impacts of severe network disruptions on activity-travel choices. A prototype of the model system is developed and implemented for a portion of the Greater Phoenix metropolitan area in Arizona to demonstrate the capabilities of the model system.
ContributorsKonduri, Karthik Charan (Author) / Pendyala, Ram M. (Thesis advisor) / Ahn, Soyoung (Committee member) / Kuby, Michael (Committee member) / Kaloush, Kamil (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Measuring the success of a transportation project as it is envisioned in the Regional Transportation Plan (RTP) and is detailed in an Environmental Impact Statement (EIS) is not part of any current planning process, for a post construction analysis may have political consequences for the project participants, would incur additional

Measuring the success of a transportation project as it is envisioned in the Regional Transportation Plan (RTP) and is detailed in an Environmental Impact Statement (EIS) is not part of any current planning process, for a post construction analysis may have political consequences for the project participants, would incur additional costs, and may be difficult to define in terms of scope. With local, state and federal budgets shrinking, funding sources are demanding that the performance of a project be evaluated and project stakeholders be held accountable. The Transportation Research Board (TRB) developed a framework that allows transportation agencies to customize their reporting so that a project's performance can be measured. In the case of the Red Mountain Freeway, the selected performance measure allows for comparing the population forecasts, the traffic volumes, and the project costs defined in the final EIS to actual population growth, actual average annual daily traffic (ADT), and actual project costs obtained from census data, the City of Mesa, and contractor bids, respectively. The results show that population projections for both Maricopa County and the City of Mesa are within less than half a percent of the actual annual population growth. The traffic analysis proved more difficult due to inconsistencies within the EIS documents, variations in the local arterials used to produce traffic volume, and in the projection time-spans. The comparison for the total increase in traffic volume generated a difference of 11.34 percent and 89.30 percent. An adjusted traffic volume equal to all local arterials and US 60 resulted in a difference of 40 percent between the projected and actual ADT values. As for the project cost comparison, not only were the costs within the individual documents inconsistent, but they were underestimated by as much as 75 percent. Evaluating the goals as described in an EIS document using the performance measure guidelines provided by the TRB may provide the tool that can help promote conflict resolution for political issues that arise, streamline the planning process, and measure the performance of the transportation system, so that lessons learned can be applied to future projects.
ContributorsKizior, Angelika (Author) / Golub, Aaron (Thesis advisor) / Kuby, Michael (Committee member) / Wentz, Elizabeth (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Alternative fuel vehicles (AFVs) have seen increased attention as a way to reduce reliance on petroleum for transportation, but adoption rates lag behind conventional vehicles. One crucial barrier to their proliferation is the lack of a convenient refueling infrastructure, and there is not a consensus on how to locate initial

Alternative fuel vehicles (AFVs) have seen increased attention as a way to reduce reliance on petroleum for transportation, but adoption rates lag behind conventional vehicles. One crucial barrier to their proliferation is the lack of a convenient refueling infrastructure, and there is not a consensus on how to locate initial stations. Some approaches recommend placing stations near where early adopters live. An alternate group of methods places stations along busy travel routes that drivers from across the metropolitan area traverse each day. To assess which theoretical approach is most appropriate, drivers of compressed natural gas (CNG) vehicles in Southern California were surveyed at stations while they refueled. Through GIS analysis, results demonstrate that respondents refueled on the way between their origins and destinations ten times more often than they refueled near their home, when no station satisfied both criteria. Freeway interchanges, which carry high daily passing traffic volumes in metropolitan areas, can be appropriate locations for initial stations based on these results. Stations cannot actually be built directly at these interchange sites, so suitable locations on nearby street networks must be chosen. A network GIS method is developed to assess street network locations' ability to capture all traffic passing through 72 interchanges in greater Los Angeles, using deviation from a driver's shortest path as the metric to assess a candidate site's suitability. There is variation in the ability of these locations to capture passing traffic both within and across interchanges, but only 7% of sites near interchanges can conveniently capture all travel directions passing through the interchange, indicating that an ad hoc station location strategy is unlikely to succeed. Surveys were then conducted at CNG stations near freeway interchanges to assess how drivers perceive and access refueling stations in these environments. Through comparative analysis of drivers' perceptions of stations, consideration of their choice sets, and the observed frequency of the use of a freeway to both access and leave these stations, results indicate that initial AFV stations near freeway interchanges can play an important role in regional AFV infrastructure.
ContributorsKelley, Scott (Author) / Kuby, Michael (Thesis advisor) / Wentz, Elizabeth (Committee member) / Pendyala, Ram (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Carbon Capture and Storage (CCS) is a climate stabilization strategy that prevents CO2 emissions from entering the atmosphere. Despite its benefits, impactful CCS projects require large investments in infrastructure, which could deter governments from implementing this strategy. In this sense, the development of innovative tools to support large-scale cost-efficient CCS

Carbon Capture and Storage (CCS) is a climate stabilization strategy that prevents CO2 emissions from entering the atmosphere. Despite its benefits, impactful CCS projects require large investments in infrastructure, which could deter governments from implementing this strategy. In this sense, the development of innovative tools to support large-scale cost-efficient CCS deployment decisions is critical for climate change mitigation. This thesis proposes an improved mathematical formulation for the scalable infrastructure model for CCS (SimCCS), whose main objective is to design a minimum-cost pipe network to capture, transport, and store a target amount of CO2. Model decisions include source, reservoir, and pipe selection, as well as CO2 amounts to capture, store, and transport. By studying the SimCCS optimal solution and the subjacent network topology, new valid inequalities (VI) are proposed to strengthen the existing mathematical formulation. These constraints seek to improve the quality of the linear relaxation solutions in the branch and bound algorithm used to solve SimCCS. Each VI is explained with its intuitive description, mathematical structure and examples of resulting improvements. Further, all VIs are validated by assessing the impact of their elimination from the new formulation. The validated new formulation solves the 72-nodes Alberta problem up to 7 times faster than the original model. The upgraded model reduces the computation time required to solve SimCCS in 72% of randomly generated test instances, solving SimCCS up to 200 times faster. These formulations can be tested and then applied to enhance variants of the SimCCS and general fixed-charge network flow problems. Finally, an experience from testing a Benders decomposition approach for SimCCS is discussed and future scope of probable efficient solution-methods is outlined.
ContributorsLobo, Loy Joseph (Author) / Sefair, Jorge A (Thesis advisor) / Escobedo, Adolfo (Committee member) / Kuby, Michael (Committee member) / Middleton, Richard (Committee member) / Arizona State University (Publisher)
Created2017