Matching Items (5)
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- All Subjects: Grassland restoration
- All Subjects: Carbon Sequestration
- All Subjects: Bipyridine
- Creators: Green, Douglas
- Resource Type: Text
- Status: Published
Description
Grassland habitat restoration activities are occurring within the semi-arid grasslands of the Agua Fria National Monument located 65 km north of Phoenix, AZ. The goal of these restoration activities is to reduce woody species encroachment, remove lignified plant materials and recycle nutrients within the ecosystem thus improving range conditions for both wildlife species and livestock. Broadcast burning, juniper thinning and slash pile burns are the principle tools used to accomplish resource objectives. Line cover, belt transect, densities, heights and biomass of vegetation data were collected to determine the response of the vegetative community to habitat restoration activities. Principal Component Analysis (PCA) was used to reduce data analysis to the more influential factors. Regression analysis was conducted for statistically significant response variables. Quadratic regression analysis found low predictive values. In broadcast burn treatment units, all important factors as identified by PCA had low predictive factors but significantly differed (R2 <0.01, p<0.05) between unburned and the years post treatment. Regression analysis found significant, albeit weak, relationships between time since treatment and independent variables. In pile burn treatment units, data reduction by PCA was not possible in a biologically meaningful way due to the high variability within treatment units. This suggests the effect of juniper encroachment on grassland vegetation persists long after junipers have been cut and burned. This study concluded that broadcast burning of the central Arizona grasslands does significantly alter many components of the vegetative community. Fuels treatments generally initially reduced both perennial woody species and grasses in number and height for two year post fire. However, palatable shrubs, in particular shrubby buckwheat, were not significantly different in broadcast burn treatment areas. The vegetative community characteristics of juniper encroached woodlands of central Arizona are unaffected by the removal and burning of junipers aside from the removal of hiding cover for predators for multiple years. It is recommended that habitat restoration activities continue provided the needs of wildlife are considered, especially pronghorn, with the incorporation of state and transition models specific to each of the respective ecological site descriptions and with the consideration of the effects of fire to pronghorn fawning habitat.
ContributorsSitzmann, Paul Roman (Author) / Miller, William (Thesis advisor) / Alford, Eddie (Committee member) / Green, Douglas (Committee member) / Arizona State University (Publisher)
Created2014
Description
Increasing concentrations of carbon dioxide in the atmosphere will inevitably lead to long-term changes in climate that can have serious consequences. Controlling anthropogenic emission of carbon dioxide into the atmosphere, however, represents a significant technological challenge. Various chemical approaches have been suggested, perhaps the most promising of these is based on electrochemical trapping of carbon dioxide using pyridine and derivatives. Optimization of this process requires a detailed understanding of the mechanisms of the reactions of reduced pyridines with carbon dioxide, which are not currently well known. This thesis describes a detailed mechanistic study of the nucleophilic and Bronsted basic properties of the radical anion of bipyridine as a model pyridine derivative, formed by one-electron reduction, with particular emphasis on the reactions with carbon dioxide. A time-resolved spectroscopic method was used to characterize the key intermediates and determine the kinetics of the reactions of the radical anion and its protonated radical form. Using a pulsed nanosecond laser, the bipyridine radical anion could be generated in-situ in less than 100 ns, which allows fast reactions to be monitored in real time. The bipyridine radical anion was found to be a very powerful one-electron donor, Bronsted base and nucleophile. It reacts by addition to the C=O bonds of ketones with a bimolecular rate constant around 1* 107 M-1 s-1. These are among the fastest nucleophilic additions that have been reported in literature. Temperature dependence studies demonstrate very low activation energies and large Arrhenius pre-exponential parameters, consistent with very high reactivity. The kinetics of E2 elimination, where the radical anion acts as a base, and SN2 substitution, where the radical anion acts as a nucleophile, are also characterized by large bimolecular rate constants in the range ca. 106 - 107 M-1 s-1. The pKa of the bipyridine radical anion was measured using a kinetic method and analysis of the data using a Marcus theory model for proton transfer. The bipyridine radical anion is found to have a pKa of 40±5 in DMSO. The reorganization energy for the proton transfer reaction was found to be 70±5 kJ/mol. The bipyridine radical anion was found to react very rapidly with carbon dioxide, with a bimolecular rate constant of 1* 108 M-1 s-1 and a small activation energy, whereas the protonated radical reacted with carbon dioxide with a rate constant that was too small to measure. The kinetic and thermodynamic data obtained in this work can be used to understand the mechanisms of the reactions of pyridines with carbon dioxide under reducing conditions.
ContributorsRanjan, Rajeev (Author) / Gould, Ian R (Thesis advisor) / Buttry, Daniel A (Thesis advisor) / Yarger, Jeff (Committee member) / Seo, Dong-Kyun (Committee member) / Arizona State University (Publisher)
Created2015
Description
ABSTRACT
Modern management techniques to maintain rangelands and deter encroachment of juniper into grassland habitats currently includes fire prescription. Additionally, a large body of research has indicated that fire has multiple benefits to grasslands resulting in increased diversity of flora and fauna. In the semi-arid grassland of the Agua Fria National Monument, fire treatments may be able to provide similar advantages. This study considers two methods of fire prescription on the Agua Fria National Monument within central Arizona: 1) Juniper thinning with pile burning; 2) Broadcast burning.
The Agua Fria National Monument upland ecosystem has limited research focusing on semi-arid grassland and juniper stand’s response to implemented treatments over time. The four year monitoring duration of this study aids in assessing the outcome of treatments and reaching the objectives of the management plan.
Vegetation in 981 quadrats was measured for species richness, cover, densities, height, and biomass during the fire prescription period from 2009 through 2013. The study was divided into two treatment types: 1) Juniper cutting and pile burn; 2) Broadcast burn areas in open grasslands.
Results of this study provide consistent examples of vegetative change and community movement towards positive response. Percent composition of overall vegetation is 5 – 30% with >50% of litter, bare ground and rock cover. Juniper sites have immediate consequences from tree thinning activities that may be beneficial to wildlife, particularly as connective corridors pronghorn antelope. Grass height was significantly reduced as well as forb density. Forbs that are highly responsive to environmental factors indicate an increase after the second year. Analysis results from grasslands indicated that cactus and unpalatable shrubs are reduced by fire but a return to pre-burn conditions occur by the third year after fire disturbance. Percent cover of perennial grasses has shown a slow increase. Wright’s buckwheat, a palatable shrub, has increased in density and height, indicating fire adaptations in the species. Species richness was reduced in the first year but increase in density continues into the third year after burn.
Modern management techniques to maintain rangelands and deter encroachment of juniper into grassland habitats currently includes fire prescription. Additionally, a large body of research has indicated that fire has multiple benefits to grasslands resulting in increased diversity of flora and fauna. In the semi-arid grassland of the Agua Fria National Monument, fire treatments may be able to provide similar advantages. This study considers two methods of fire prescription on the Agua Fria National Monument within central Arizona: 1) Juniper thinning with pile burning; 2) Broadcast burning.
The Agua Fria National Monument upland ecosystem has limited research focusing on semi-arid grassland and juniper stand’s response to implemented treatments over time. The four year monitoring duration of this study aids in assessing the outcome of treatments and reaching the objectives of the management plan.
Vegetation in 981 quadrats was measured for species richness, cover, densities, height, and biomass during the fire prescription period from 2009 through 2013. The study was divided into two treatment types: 1) Juniper cutting and pile burn; 2) Broadcast burn areas in open grasslands.
Results of this study provide consistent examples of vegetative change and community movement towards positive response. Percent composition of overall vegetation is 5 – 30% with >50% of litter, bare ground and rock cover. Juniper sites have immediate consequences from tree thinning activities that may be beneficial to wildlife, particularly as connective corridors pronghorn antelope. Grass height was significantly reduced as well as forb density. Forbs that are highly responsive to environmental factors indicate an increase after the second year. Analysis results from grasslands indicated that cactus and unpalatable shrubs are reduced by fire but a return to pre-burn conditions occur by the third year after fire disturbance. Percent cover of perennial grasses has shown a slow increase. Wright’s buckwheat, a palatable shrub, has increased in density and height, indicating fire adaptations in the species. Species richness was reduced in the first year but increase in density continues into the third year after burn.
ContributorsCole-Snow, Kimberly Sue (Author) / Alford, Eddie (Thesis advisor) / Miller, William (Committee member) / Green, Douglas (Committee member) / Arizona State University (Publisher)
Created2015
Description
ABSTRACT The February 2008 study of a Snowflake, Arizona site measured changes in soil organic carbon, total nitrogen, extractable phosphorus, and soil moisture, to determine what affect One-seed Juniper (Juniperus monosperma) trees have on surrounding soil, thus affecting native grass growth. Increasing juniper densities in grasslands also decrease populations of some grassland bird species. Measurements were taken each meter along a twelve meter line transect, moving from juniper trees, through a bare soil area and into a grassland. Non-linear relationships were examined, in regard to distance from the tree and juniper root mass. Relationships were examined to determine any affect of the juniper tree on soil characteristics along the transect. Organic carbon decreased as distance increased from the trees (F=4.25, df=46, p=0.020). Soil moisture increased with distance from the trees (F=5.42, df=46, p=0.008), and juniper root mass, of roots less than 1 mm diameter, significantly decreased with distance away from the trees (F=11.29, df=46, p=0.0001). Total nitrogen and extractable phosphorus did not significantly change with distance from the tree, or presence of juniper roots. This data is important as grassland restoration projects rely on the availability of soil nutrients and water for reestablishment of native grass species.
ContributorsWeller, Christopher (Author) / Green, Douglas (Thesis advisor) / Miller, William H. (Committee member) / Alford, Edward (Committee member) / Arizona State University (Publisher)
Created2010
Description
Despite public demand for climate change mitigation and natural open space conservancy, existing political and design efforts are only beginning to address the declining efficacy of the biotic carbon pool (C-pool) to sequester carbon. Advances in understanding of biogeochemical processes have provided methods for estimating carbon embodied in natural open spaces and enhancing carbon sequestration efficacy. In this study, the benefits of carbon embodied in dryland open spaces are determined by estimating carbon flux and analyzing ecological, social, and economic benefits provided by sequestered carbon. Understanding the ecological processes and derived benefits of carbon exchange in dryland open spaces will provide insight into enhancing carbon sequestration efficacy. Open space carbon is estimated by calculating the amount of carbon sequestration (estimated in Mg C / ha / y) in dryland open space C-pools. Carbon sequestration in dryland open spaces can be summarized in five open space typologies: hydric, mesic, aridic, biomass for energy agriculture, and traditional agriculture. Hydric (wetland) systems receive a significant amount of moisture; mesic (riparian) systems receive a moderate amount of moisture; and aridic (dry) systems receive low amounts of moisture. Biomass for energy production (perennial biomass) and traditional agriculture (annual / traditional biomass) can be more effective carbon sinks if managed appropriately. Impacts of design interventions to the carbon capacity of dryland open space systems are calculated by estimating carbon exchange in existing open space (base case) compared to projections of carbon sequestered in a modified system (prototype design). A demonstration project at the Lower San Pedro River Watershed highlights the potential for enhancing carbon sequestration. The site-scale demonstration project takes into account a number of limiting factors and opportunities including: availability of water and ability to manipulate its course, existing and potential vegetation, soil types and use of carbon additives, and land-use (particularly agriculture). Specific design challenges to overcome included: restoring perennial water to the Lower San Pedro River, reestablishing hydric and mesic systems, linking fragmented vegetation, and establishing agricultural systems that provide economic opportunities and act as carbon sinks. The prototype design showed enhancing carbon sequestration efficacy by 128-133% is possible with conservative design interventions.
ContributorsHuck, Erick (Author) / Cook, Edward (Thesis advisor) / Green, Douglas (Committee member) / Brooks, Kenneth (Committee member) / Montemayor, Gabriel (Committee member) / Arizona State University (Publisher)
Created2012