Matching Items (177)
Description
The finite supply of current energy production materials has created opportunities for the investigation of alternative energy sources in many fields. One example is the use of microorganisms in bioenergy applications, such as microbial fuel cells. Present in many types of environments, microorganisms with the ability to respire solid electron acceptors have become of increasing relevance to alternative energy and wastewater treatment research. In this dissertation, several aspects of anode respiration are investigated, with the goal of increasing the limited understanding of the mechanisms of electron transport through the use of advanced electrochemical methods. Biofilms of Geobacter sulfurreducens, the model anode respiring organism, as well as its alkaliphilic relative, Geoalkalibacter ferrihydriticus, were investigated using chronoamperometry, electrochemical impedance spectroscopy, and cyclic voltammetry.
In G. sulfurreducens, two distinct pathways of electron transport were observed through the application of advanced electrochemical techniques on anode biofilms in microbial electrochemical cells. These pathways were found to be preferentially expressed, based on the poised anode potential (redox potential) of the electrode. In Glk. ferrihydriticus, four pathways for electron transport were found, showing an even greater diversity in electron transport pathway utilization as compared to G. sulfurreducens. These observations provide insights into the diversity of electron transport pathways present in anode-respiring bacteria and introduce the necessity of further characterization for pathway identification.
Essential to science today, communication of pressing scientific issues to the lay audience may present certain difficulties. This can be seen especially with the topics that are considered socio-scientific issues, those considered controversial in society but not for scientists. This dissertation explores the presentation of alternative and renewable energy technologies and climate change in undergraduate education. In introductory-level Biology, Chemistry, and Physics textbooks, the content and terminology presented were analyzed for individual textbooks and used to evaluate discipline-based trends. Additional extensions were made between teaching climate change with the active learning technique of citizen science using past research gains from studies of evolution. These observations reveal patterns in textbook content for energy technologies and climate change, as well as exploring new aspects of teaching techniques.
In G. sulfurreducens, two distinct pathways of electron transport were observed through the application of advanced electrochemical techniques on anode biofilms in microbial electrochemical cells. These pathways were found to be preferentially expressed, based on the poised anode potential (redox potential) of the electrode. In Glk. ferrihydriticus, four pathways for electron transport were found, showing an even greater diversity in electron transport pathway utilization as compared to G. sulfurreducens. These observations provide insights into the diversity of electron transport pathways present in anode-respiring bacteria and introduce the necessity of further characterization for pathway identification.
Essential to science today, communication of pressing scientific issues to the lay audience may present certain difficulties. This can be seen especially with the topics that are considered socio-scientific issues, those considered controversial in society but not for scientists. This dissertation explores the presentation of alternative and renewable energy technologies and climate change in undergraduate education. In introductory-level Biology, Chemistry, and Physics textbooks, the content and terminology presented were analyzed for individual textbooks and used to evaluate discipline-based trends. Additional extensions were made between teaching climate change with the active learning technique of citizen science using past research gains from studies of evolution. These observations reveal patterns in textbook content for energy technologies and climate change, as well as exploring new aspects of teaching techniques.
ContributorsYoho, Rachel Ann (Author) / Torres, César I (Thesis advisor) / Rittmann, Bruce E. (Committee member) / Popat, Sudeep C (Committee member) / Vanmali, Binaben H (Committee member) / Arizona State University (Publisher)
Created2016
Description
Energy use within urban building stocks is continuing to increase globally as populations expand and access to electricity improves. This projected increase in demand could require deployment of new generation capacity, but there is potential to offset some of this demand through modification of the buildings themselves. Building stocks are quasi-permanent infrastructures which have enduring influence on urban energy consumption, and research is needed to understand: 1) how development patterns constrain energy use decisions and 2) how cities can achieve energy and environmental goals given the constraints of the stock. This requires a thorough evaluation of both the growth of the stock and as well as the spatial distribution of use throughout the city. In this dissertation, a case study in Los Angeles County, California (LAC) is used to quantify urban growth, forecast future energy use under climate change, and to make recommendations for mitigating energy consumption increases. A reproducible methodological framework is included for application to other urban areas.
In LAC, residential electricity demand could increase as much as 55-68% between 2020 and 2060, and building technology lock-in has constricted the options for mitigating energy demand, as major changes to the building stock itself are not possible, as only a small portion of the stock is turned over every year. Aggressive and timely efficiency upgrades to residential appliances and building thermal shells can significantly offset the projected increases, potentially avoiding installation of new generation capacity, but regulations on new construction will likely be ineffectual due to the long residence time of the stock (60+ years and increasing). These findings can be extrapolated to other U.S. cities where the majority of urban expansion has already occurred, such as the older cities on the eastern coast. U.S. population is projected to increase 40% by 2060, with growth occurring in the warmer southern and western regions. In these growing cities, improving new construction buildings can help offset electricity demand increases before the city reaches the lock-in phase.
In LAC, residential electricity demand could increase as much as 55-68% between 2020 and 2060, and building technology lock-in has constricted the options for mitigating energy demand, as major changes to the building stock itself are not possible, as only a small portion of the stock is turned over every year. Aggressive and timely efficiency upgrades to residential appliances and building thermal shells can significantly offset the projected increases, potentially avoiding installation of new generation capacity, but regulations on new construction will likely be ineffectual due to the long residence time of the stock (60+ years and increasing). These findings can be extrapolated to other U.S. cities where the majority of urban expansion has already occurred, such as the older cities on the eastern coast. U.S. population is projected to increase 40% by 2060, with growth occurring in the warmer southern and western regions. In these growing cities, improving new construction buildings can help offset electricity demand increases before the city reaches the lock-in phase.
ContributorsReyna, Janet Lorel (Author) / Chester, Mikhail V (Thesis advisor) / Gurney, Kevin (Committee member) / Reddy, T. Agami (Committee member) / Rey, Sergio (Committee member) / Arizona State University (Publisher)
Created2016
Description
Drawing from the fields of coastal geography, political ecology, and institutions, this dissertation uses Cape Cod, MA, as a case study, to investigate how chronic and acute climate-related coastal hazards, socio-economic characteristics, and governance and decision-making interact to produce more resilient or at-risk coastal communities. GIS was used to model the impacts of sea level rise (SLR) and hurricane storm surge scenarios on natural and built infrastructure. Social, gentrification, and tourism indices were used to identify communities differentially vulnerable to coastal hazards. Semi-structured interviews with planners and decision-makers were analyzed to examine hazard mitigation planning.
The results of these assessments demonstrate there is considerable variation in coastal hazard impacts across Cape Cod towns. First, biophysical vulnerability is highly variable with the Outer Cape (e.g., Provincetown) at risk for being temporarily and/or permanently isolated from the rest of the county. In most towns, a Category 1 accounts for the majority of inundation with impacts that will be intensified by SLR. Second, gentrification in coastal communities can create new social vulnerabilities by changing economic bases and disrupting communities’ social networks making it harder to cope. Moreover, higher economic dependence on tourism can amplify towns’ vulnerability with reduced capacities to recover. Lastly, low political will is an important barrier to effective coastal hazard mitigation planning and implementation particularly given the power and independence of town government on Cape Cod. Despite this independence, collaboration will be essential for addressing the trans-boundary effects of coastal hazards and provide an opportunity for communities to leverage their limited resources for long-term hazard mitigation planning.
This research contributes to the political ecology of hazards and vulnerability research by drawing from the field of institutions, by examining how decision-making processes shape vulnerabilities and capacities to plan and implement mitigation strategies. While results from this research are specific to Cape Cod, it demonstrates a broader applicability of the “Hazards, Vulnerabilities, and Governance” framework for assessing other hazards (e.g., floods, fires, etc.). Since there is no “one-size-fits-all” approach to mitigating coastal hazards, examining vulnerabilities and decision-making at local scales is necessary to make resiliency and mitigation efforts specific to communities’ needs.
The results of these assessments demonstrate there is considerable variation in coastal hazard impacts across Cape Cod towns. First, biophysical vulnerability is highly variable with the Outer Cape (e.g., Provincetown) at risk for being temporarily and/or permanently isolated from the rest of the county. In most towns, a Category 1 accounts for the majority of inundation with impacts that will be intensified by SLR. Second, gentrification in coastal communities can create new social vulnerabilities by changing economic bases and disrupting communities’ social networks making it harder to cope. Moreover, higher economic dependence on tourism can amplify towns’ vulnerability with reduced capacities to recover. Lastly, low political will is an important barrier to effective coastal hazard mitigation planning and implementation particularly given the power and independence of town government on Cape Cod. Despite this independence, collaboration will be essential for addressing the trans-boundary effects of coastal hazards and provide an opportunity for communities to leverage their limited resources for long-term hazard mitigation planning.
This research contributes to the political ecology of hazards and vulnerability research by drawing from the field of institutions, by examining how decision-making processes shape vulnerabilities and capacities to plan and implement mitigation strategies. While results from this research are specific to Cape Cod, it demonstrates a broader applicability of the “Hazards, Vulnerabilities, and Governance” framework for assessing other hazards (e.g., floods, fires, etc.). Since there is no “one-size-fits-all” approach to mitigating coastal hazards, examining vulnerabilities and decision-making at local scales is necessary to make resiliency and mitigation efforts specific to communities’ needs.
ContributorsGentile, Lauren Elyse (Author) / Bolin, Bob (Thesis advisor) / Wentz, Elizabeth (Committee member) / White, Dave (Committee member) / York, Abigail (Committee member) / Arizona State University (Publisher)
Created2016
Description
This thesis examines the use of the moisture swing resin materials employed at the Center for Negative Carbon Emissions (CNCE) in order to provide carbon dioxide from ambient air to photobioreactors containing extremophile cyanobacteria cultured at the Arizona Center for Algae Technology and Innovation (AzCATI). For this purpose, a carbon dioxide feeding device was designed, built, and tested. The results indicate how much resin should be used with a given volume of algae medium: approximately 500 grams of resin can feed 1% CO2 at about three liters per minute to a ten liter medium of the Galdieria sulphuraria 5587.1 strain for one hour (equivalent to about 0.1 grams of carbon dioxide per hour per seven grams of algae). Using the resin device, the algae grew within their normal growth range: 0.096 grams of ash-free dry weight per liter over a six hour period. Future applications in which the resin-to-algae process can be utilized are discussed.
ContributorsBeaubien, Courtney (Author) / Lackner, Klaus (Thesis advisor) / Lammers, Peter (Committee member) / Atkins, Steve (Committee member) / Arizona State University (Publisher)
Created2016
Description
In the American Southwest, an area which already experiences a significant number of cooling degree days, anthropogenic climate change is expected to result in higher average temperatures and the increasing frequency, duration, and severity of heat waves. Climatological forecasts predict heat waves will increase by 150-840% in Los Angeles County, California and 340-1800% in Maricopa County, Arizona. Heat exposure is known to increase both morbidity and mortality and rising temperatures represent a threat to public health. As a result there has been a significant amount of research into understanding existing socio-economic vulnerabilities to extreme heat which has identified population subgroups at greater risk of adverse health outcomes. Additionally, research has shown that man-made infrastructure can mitigate or exacerbate these health risks. However, while recent socio-economic heat vulnerability research has developed geospatially explicit results, research which links it directly with infrastructure characteristics is limited. Understanding how socio-economic vulnerabilities interact with infrastructure systems is a critical component to developing climate adaptation policies and programs which efficiently and effectively mitigate health risks associated with rising temperatures.
The availability of cooled space, whether public or private, has been shown to greatly reduce health risks associated with extreme heat. However, a lack of fine-scale knowledge of which households have access to this infrastructure results in an incomplete understanding of the health risks associated with heat. This knowledge gap could result in the misallocation of resources intended to mitigate negative health impacts associated with heat exposure. Additionally, when discussing accessibility to public cooled space there are underlying questions of mobility and mode choice. In addition to captive riders, a growing emphasis on walking, biking and public transit will likely expose additional choice riders to extreme temperatures and compound existing vulnerabilities to heat.
The availability of cooled space, whether public or private, has been shown to greatly reduce health risks associated with extreme heat. However, a lack of fine-scale knowledge of which households have access to this infrastructure results in an incomplete understanding of the health risks associated with heat. This knowledge gap could result in the misallocation of resources intended to mitigate negative health impacts associated with heat exposure. Additionally, when discussing accessibility to public cooled space there are underlying questions of mobility and mode choice. In addition to captive riders, a growing emphasis on walking, biking and public transit will likely expose additional choice riders to extreme temperatures and compound existing vulnerabilities to heat.
ContributorsFraser, Andrew Michael (Author) / Chester, Mikhail (Thesis advisor) / Seager, Thomas (Committee member) / Zhou, Xuesong (Committee member) / Kuby, Michael (Committee member) / Arizona State University (Publisher)
Created2016
Description
Energy consumption in buildings, accounting for 41% of 2010 primary energy consumption in the United States (US), is particularly vulnerable to climate change due to the direct relationship between space heating/cooling and temperature. Past studies have assessed the impact of climate change on long-term mean and/or peak energy demands. However, these studies usually neglected spatial variations in the “balance point” temperature, population distribution effects, air-conditioner (AC) saturation, and the extremes at smaller spatiotemporal scales, making the implications of local-scale vulnerability incomplete. Here I develop empirical relationships between building energy consumption and temperature to explore the impact of climate change on long-term mean and extremes of energy demand, and test the sensitivity of these impacts to various factors. I find increases in summertime electricity demand exceeding 50% and decreases in wintertime non-electric energy demand of more than 40% in some states by the end of the century. The occurrence of the most extreme (appearing once-per-56-years) electricity demand increases more than 2600 fold, while the occurrence of the once per year extreme events increases more than 70 fold by the end of this century. If the changes in population and AC saturation are also accounted for, the impact of climate change on building energy demand will be exacerbated.
Using the individual building energy simulation approach, I also estimate the impact of climate change to different building types at over 900 US locations. Large increases in building energy consumption are found in the summer, especially during the daytime (e.g., >100% increase for warehouses, 5-6 pm). Large variation of impact is also found within climate zones, suggesting a potential bias when estimating climate-zone scale changes with a small number of representative locations.
As a result of climate change, the building energy expenditures increase in some states (as much as $3 billion/year) while in others, costs decline (as much as $1.4 billion/year). Integrated across the contiguous US, these variations result in a net savings of roughly $4.7 billion/year. However, this must be weighed against the cost (exceeding $19 billion) of adding electricity generation capacity in order to maintain the electricity grid’s reliability in summer.
Using the individual building energy simulation approach, I also estimate the impact of climate change to different building types at over 900 US locations. Large increases in building energy consumption are found in the summer, especially during the daytime (e.g., >100% increase for warehouses, 5-6 pm). Large variation of impact is also found within climate zones, suggesting a potential bias when estimating climate-zone scale changes with a small number of representative locations.
As a result of climate change, the building energy expenditures increase in some states (as much as $3 billion/year) while in others, costs decline (as much as $1.4 billion/year). Integrated across the contiguous US, these variations result in a net savings of roughly $4.7 billion/year. However, this must be weighed against the cost (exceeding $19 billion) of adding electricity generation capacity in order to maintain the electricity grid’s reliability in summer.
ContributorsHuang, Jianhua (Author) / Gurney, Kevin Robert (Thesis advisor) / Miller, Clark Anson (Committee member) / Rey, Sergio J (Committee member) / Georgescu, Matei (Committee member) / Arizona State University (Publisher)
Created2016
Description
Rapid urban expansion and the associated landscape modifications have led to significant changes of surface processes in built environments. These changes further interact with the overlying atmospheric boundary layer and strongly modulate urban microclimate. To capture the impacts of urban land surface processes on urban boundary layer dynamics, a coupled urban land-atmospheric modeling framework has been developed. The urban land surface is parameterized by an advanced single-layer urban canopy model (SLUCM) with realistic representations of urban green infrastructures such as lawn, tree, and green roof, etc. The urban atmospheric boundary layer is simulated by a single column model (SCM) with both convective and stable schemes. This coupled SLUCM-SCM framework can simulate the time evolution and vertical profile of different meteorological variables such as virtual potential temperature, specific humidity and carbon dioxide concentration. The coupled framework has been calibrated and validated in the metropolitan Phoenix area, Arizona. To quantify the model sensitivity, an advanced stochastic approach based on Markov-Chain Monte Carlo procedure has been applied. It is found that the development of urban boundary layer is highly sensitive to surface characteristics of built terrains, including urban land use, geometry, roughness of momentum, and vegetation fraction. In particular, different types of urban vegetation (mesic/xeric) affect the boundary layer dynamics through different mechanisms. Furthermore, this framework can be implanted into large-scale models such as Weather Research and Forecasting model to assess the impact of urbanization on regional climate.
ContributorsSong, Jiyun (Author) / Wang, Zhihua (Thesis advisor) / Vivoni, Enrique R (Committee member) / Mascaro, Giuseppe (Committee member) / Myint, Soe W (Committee member) / Sailor, David (Committee member) / Arizona State University (Publisher)
Created2016
Description
The Basin and Range province of southwestern USA are composed of different grassland and shrubland ecosystems. Particularly understudied ecosystems in this region are playas, which are ephemerally-flooded wetlands located in topographic low areas of hydrologically-closed dryland catchments. There is not much known about the ecological functioning of playas and the role of playas within desert basins. Even less is known about how global change drivers may affect playas in the future. The main objective of this thesis was to better understand the ecological functioning and the impact of climate change on desert playa wetlands. I collected new data, used existing long-term data, and used simulation modelling techniques to address this objective. I compared playa soils to upland soils and found that playas were hotspots of soil organic carbon and nutrient storage within a desert basin. I also used existing data to analyze the response of above-ground net primary productivity (ANPP) to annual precipitation in playas and upland ecosystems. I found that playa ANPP responded in a non-linear concave-down relationship with annual precipitation amount. Playa ANPP peaked in moderately wet years and declined in very wet years, which was most likely due to flooding; whereas, upland ANPP increased linearly with precipitation. I measured soil organic carbon and nitrogen concentrations in a representative subset of playas and measured the biophysical characteristics of the upland catchments associated with each playa. I found that both catchment geomorphology and vegetation cover were correlated to differences in soil organic carbon and nitrogen among playas. These results showed the importance external soil-inputs delivered via surface runon to playas. Finally, I empirically measured groundwater recharge beneath playas and combined these empirical data with modelling data to forecast how playa groundwater recharge may change in the future. I concluded that playas contribute to groundwater recharge in desert aquifers, playa runon is a strong predictor of playa groundwater recharge, and climate change will have a net-positive impact on groundwater recharge beneath playas. Overall, my thesis research increased the understanding of the role of desert playas on the functioning of dryland ecosystems.
ContributorsMcKenna, Philip (Author) / Sala, Osvaldo E. (Thesis advisor) / Monger, H. Curtis (Committee member) / Hall, Sharon J (Committee member) / Childers, Daniel L. (Committee member) / Arizona State University (Publisher)
Created2016
Description
Water resource systems have provided vital support to transformative growth in the Southwest United States; and for more than a century the Salt River Project (SRP) has served as a model of success among multipurpose federal reclamation projects, currently delivering approximately 40% of water demand in the metropolitan Phoenix area. Drought concerns have sensitized water management to risks posed by natural variability and forthcoming climate change.
Full simulations originating in climate modeling have been the conventional approach to impacts assessment. But, once debatable climate projections are applied to hydrologic models challenged to accurately represent the region’s arid hydrology, the range of possible scenarios enlarges as uncertainties propagate through sequential levels of modeling complexity. Numerous issues render future projections frustratingly uncertain, leading many researchers to conclude it will be some decades before hydroclimatic modeling can provide specific and useful information to water management.
Alternatively, this research investigation inverts the standard approach to vulnerability assessment and begins with characterization of the threatened system, proceeding backwards to the uncertain climate future. Thorough statistical analysis of historical watershed climate and runoff enabled development of (a) a stochastic simulation methodology for net basin supply (NBS) that renders the entire range of droughts, and (b) hydrologic sensitivities to temperature and precipitation changes. An operations simulation model was developed for assessing the SRP reservoir system’s cumulative response to inflow variability and change. After analysis of the current system’s drought response, a set of climate change forecasts for the balance of this century were developed and translated through hydrologic sensitivities to drive alternative NBS time series assessed by reservoir operations modeling.
Statistically significant changes in key metrics were found for climate change forecasts, but the risk of reservoir depletion was found to remain zero. System outcomes fall within ranges to which water management is capable of responding. Actions taken to address natural variability are likely to be the same considered for climate change adaptation. This research approach provides specific risk assessments per unambiguous methods grounded in observational evidence in contrast to the uncertain projections thus far prepared for the region.
Full simulations originating in climate modeling have been the conventional approach to impacts assessment. But, once debatable climate projections are applied to hydrologic models challenged to accurately represent the region’s arid hydrology, the range of possible scenarios enlarges as uncertainties propagate through sequential levels of modeling complexity. Numerous issues render future projections frustratingly uncertain, leading many researchers to conclude it will be some decades before hydroclimatic modeling can provide specific and useful information to water management.
Alternatively, this research investigation inverts the standard approach to vulnerability assessment and begins with characterization of the threatened system, proceeding backwards to the uncertain climate future. Thorough statistical analysis of historical watershed climate and runoff enabled development of (a) a stochastic simulation methodology for net basin supply (NBS) that renders the entire range of droughts, and (b) hydrologic sensitivities to temperature and precipitation changes. An operations simulation model was developed for assessing the SRP reservoir system’s cumulative response to inflow variability and change. After analysis of the current system’s drought response, a set of climate change forecasts for the balance of this century were developed and translated through hydrologic sensitivities to drive alternative NBS time series assessed by reservoir operations modeling.
Statistically significant changes in key metrics were found for climate change forecasts, but the risk of reservoir depletion was found to remain zero. System outcomes fall within ranges to which water management is capable of responding. Actions taken to address natural variability are likely to be the same considered for climate change adaptation. This research approach provides specific risk assessments per unambiguous methods grounded in observational evidence in contrast to the uncertain projections thus far prepared for the region.
ContributorsMurphy, Kevin W (Author) / Cerveny, Randall S. (Thesis advisor) / Balling, Jr., Robert C. (Committee member) / Ellis, Andrew W. (Committee member) / Skindlov, Jon A. (Committee member) / Arizona State University (Publisher)
Created2016
Description
Climate change poses a threat to the emotional well-being and livelihood strategies of individuals in biophysically vulnerable communities. While the biophysical effects and possibilities of climate change are well-documented, understanding the emotional impacts on individuals in these communities is an avenue of research that requires more exploration. Using an ethnographic approach, this study analyzes the emotional responses of individuals, first in three biophysically vulnerable communities in the United States, and second, in island communities. Study sites in the United States include Mobile, Alabama; Kodiak, Alaska; and Phoenix, Arizona, each of which have different vulnerabilities to the effects of climate change. Internationally, we conducted research in Viti Levu, Fiji; Nicosia, Cyprus; Wellington, New Zealand; and London, England. Using the 2014 Global Ethnohydrology Study Protocol respondents were asked about their emotional responses to the current effects of climate change, the effects of climate change on livelihoods in their area, and the effects of climate change on the younger generation. Using cross-cultural data allows for a broader understanding of emotional distress and wellbeing in response to climate change in areas with similar expected climate change outcomes, although with different levels of biophysical vulnerability, as well as understanding emotional distress and wellbeing in areas with different expected climate change outcomes, and similar levels of biophysical vulnerability. Results from this research can be used to understand possible mental health outcomes, the possibilities for political activism, and how to create mitigation strategies that resonate with local community members.
ContributorsDu Bray, Margaret V (Author) / Wutich, Amber (Thesis advisor) / BurnSilver, Shauna (Thesis advisor) / Bolin, Bob (Committee member) / Arizona State University (Publisher)
Created2017