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The goals of the styrene oxide adsorption experiments were to develop reliable isotherms of styrene oxide onto Dowex Optipore L-493 resin and onto mesoporous carbon adsorbents, in addition to determining the ideal conditions for styrene oxide production from E. coli. Adsorption is an effective means of separation used in industry

The goals of the styrene oxide adsorption experiments were to develop reliable isotherms of styrene oxide onto Dowex Optipore L-493 resin and onto mesoporous carbon adsorbents, in addition to determining the ideal conditions for styrene oxide production from E. coli. Adsorption is an effective means of separation used in industry to separate compounds, often organics from air and water. Styrene oxide adsorption runs without E. coli were conducted at concentrations ranging from 0.15 to 3.00 g/L with resin masses ranging from 0.1 to 0.5 g of Dowex Optipore L-493 and 0.5 to 0.75 g of mesoporous carbon adsorbent. Runs were conducted on a shake plate operating at 80 rpm for 24 hours at ambient temperature. Isotherms were developed from the results and then adsorption experiments with E. coli and L-493 were performed. Runs were conducted at glucose concentrations ranging from 20-40 g/L and resin masses of 0.100 g to 0.800 g. Samples were incubated for 72 hours and styrene oxide production was measured using an HPLC device. Specific loading values reached up to 0.356 g/g for runs without E. coli and nearly 0.003 g of styrene oxide was adsorbed by L-493 during runs with E. coli. Styrene oxide production was most effective at low resin masses and medium glucose concentrations when produced by E. coli.
ContributorsHsu, Joshua (Co-author) / Oremland, Zachary (Co-author) / Nielsen, David (Thesis director) / Staggs, Kyle (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor) / School of Sustainability (Contributor)
Created2014-05
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This thesis was conducted in order to determine the role played by food miles metrics in making the agricultural industry more sustainable. In an effort to analyze the importance of eat locally this study utilizes a partial life cycle assessment. This study looks at oranges grown in Arizona and California

This thesis was conducted in order to determine the role played by food miles metrics in making the agricultural industry more sustainable. In an effort to analyze the importance of eat locally this study utilizes a partial life cycle assessment. This study looks at oranges grown in Arizona and California and inputs such as water, energy, fertilizer, herbicide, pesticide, frost mitigation, and distance in order to conduct the partial life cycle assessment. Results of this study indicate that food miles are not as significant, in relation to overall energy input, as the locavore movement claims. This is because production processes account for a larger portion of the total energy used in the food chain than what these claims suggest. While eating locally is still a significant way of reducing energy use, this thesis shows that decisions about eating sustainably should not only focus on the distance that the products travel, but place equal, if not more, importance on energy use differences due to geographic location and in-farm operations. Future research should be completed with more comprehensive impact categories and conducted for different crops, farming, and locations. Further research is needed in order to confirm or challenge the results of this thesis. With more research conducted regarding this topic, ecological labeling of agricultural products could be improved to help consumers make the most informed choices possible.
ContributorsMaggass, Melissa Gail (Author) / Manuel-Navarrete, David (Thesis director) / Martin, Thomas (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / W. P. Carey School of Business (Contributor) / Department of Management (Contributor)
Created2014-05
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Description
Current farming demographics in the United States indicate an aging and overwhelmingly white group of farmers, stimulating the need for engaging a younger and more diverse population. There is an opportunity to engage these populations through farm-based internship and apprenticeship programs, which are immersive programs on small-scale, sustainable farms. These

Current farming demographics in the United States indicate an aging and overwhelmingly white group of farmers, stimulating the need for engaging a younger and more diverse population. There is an opportunity to engage these populations through farm-based internship and apprenticeship programs, which are immersive programs on small-scale, sustainable farms. These programs are unique in providing hands-on training, housing, meals, and a stipend in return for labor, presenting a pathway to social empowerment. The potential outcomes of increasing diversity and inclusion in farm programs are absent from the research on the benefits of diversity and inclusion in other work environments, such as the corporate setting. This paper presents the results of a study aimed at determining levels of diversity and inclusion in United States farm-based internship programs, and the viability of these programs as an effective opportunity to engage marginalized young people in farming. The study of 13 farm owners and managers across the U.S. found that the participants are focused on fostering education and training, environmental benefits, and a sense of community in their respective programs. All participants either want to establish, or believe they currently have, an inclusive workplace on their farm, but also indicated a barrier to inclusivity in the lack of a diverse applicant pool. Future recommendations for removing that barrier and involving more young, diverse interns include increased outreach and access to these programs, the use of inclusive language, and further research.
ContributorsLascola, Dania (Co-author) / Biel, Braden (Co-author) / Cloutier, Scott (Thesis director) / MacFadyen, Joshua (Committee member) / School of International Letters and Cultures (Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
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Description
The Prosopis genus of trees, also known as mesquites, are uniquely equipped to allow for an agroforestry regime in which crops can be grown beneath the canopy of the tree. Mesquites have the ability to redistribute water moisture in such a way that allows plants under the canopy to use

The Prosopis genus of trees, also known as mesquites, are uniquely equipped to allow for an agroforestry regime in which crops can be grown beneath the canopy of the tree. Mesquites have the ability to redistribute water moisture in such a way that allows plants under the canopy to use water that has been brought up by the roots of mesquite trees. This means that there is a potential for food crops to be grown under the trees without using additional irrigation measures. This could be used where access to water is limited or for a sustainability-minded farmer who is trying to reduce water inputs in an arid environment. Mesquite trees produce a variety of products, including lumber and bean pods that can be ground down into an edible flour. Both products demand a high price in the marketplace and are produced in addition to the crops that can potentially be grown beneath the mesquite tree. In order to determine whether or not it is possible to grow crops under mesquite trees, I reviewed a wide range of literature regarding hydraulic redistribution, mesquite trees in general, and what plants might be best suited for growing beneath a mesquite. The list of plants was narrowed down to four crops that seemed most likely to survive in shaded, low water conditions in a hot environment. There has not been any research done on crops growing beneath mesquite trees, so the next step for research would be to experiment with each of the crops to determine how well each species can adapt to the specified conditions.
ContributorsMesser, Luke Winston (Author) / Eakin, Hallie (Thesis director) / Hall, Sharon (Committee member) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
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Description
Metal-organic frameworks (MOFs) are a new set of porous materials comprised of metals or metal clusters bonded together in a coordination system by organic linkers. They are becoming popular for gas separations due to their abilities to be tailored toward specific applications. Zirconium MOFs in particular are known for their

Metal-organic frameworks (MOFs) are a new set of porous materials comprised of metals or metal clusters bonded together in a coordination system by organic linkers. They are becoming popular for gas separations due to their abilities to be tailored toward specific applications. Zirconium MOFs in particular are known for their high stability under standard temperature and pressure due to the strength of the Zirconium-Oxygen coordination bond. However, the acid modulator needed to ensure long range order of the product also prevents complete linker deprotonation. This leads to a powder product that cannot easily be incorporated into continuous MOF membranes. This study therefore implemented a new bi-phase synthesis technique with a deprotonating agent to achieve intergrowth in UiO-66 membranes. Crystal intergrowth will allow for effective gas separations and future permeation testing. During experimentation, successful intergrown UiO-66 membranes were synthesized and characterized. The degree of intergrowth and crystal orientations varied with changing deprotonating agent concentration, modulator concentration, and ligand:modulator ratios. Further studies will focus on achieving the same results on porous substrates.
ContributorsClose, Emily Charlotte (Author) / Mu, Bin (Thesis director) / Shan, Bohan (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-12
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Description

Is there a mismatch between urban farmers’ perceptions of their farm’s environmental sustainability and its actual environmental impact? Focusing on the use of water and nutrients on each farm as described by the farmers through interviews, it is evident that there is some level of disconnect between ideals and practices.

Is there a mismatch between urban farmers’ perceptions of their farm’s environmental sustainability and its actual environmental impact? Focusing on the use of water and nutrients on each farm as described by the farmers through interviews, it is evident that there is some level of disconnect between ideals and practices. This project may aid in bridging the gap between the two in regard to the farmers’ sustainability goals. This project will move forward by continuing interviews with farmers as well as collecting soil and water from the farms in order to more accurately quantify the sustainability of the farms’ practices. This project demonstrates that there is some degree of misalignment between perception and reality. Two farms claimed they were sustainable when their practices did not reflect that, while 2 farms said they were not sure if they were sustainable when their practices indicated otherwise. Samples from two farms showed high concentrations of nutrients and salts, supporting the idea that there may be a mismatch between perceived and actual sustainability.

ContributorsBonham, Emma Eileen (Author) / Muenich, Rebecca (Thesis director) / Zanin, Alaina (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor) / School of Sustainability (Contributor) / School of Sustainable Engineering & Built Envirnmt (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description

As technology has evolved over time and the U.S. population increases each year, this thesis focuses on the ways in which food production has shifted from the original farm to table to industrialized, processed food systems. Through a rationalization perspective, this research looks to the history and repercussions of industrial

As technology has evolved over time and the U.S. population increases each year, this thesis focuses on the ways in which food production has shifted from the original farm to table to industrialized, processed food systems. Through a rationalization perspective, this research looks to the history and repercussions of industrial agriculture as it has shifted over time. The term over-industrialization is used to operationalize the state of our current production methods. These methods focus extensively on the least expensive and most rapid methods to produce large yields of food products and pay no mind to ethics, respect of culture, land, or quality of products. Today, there is a shroud the corporations have placed over food production to ensure a “what we can’t see doesn’t affect us” belief system. In this way, the thesis provides insight on past, current, and future methods of manufacturing. I conclude that although plausible alternatives are present, continued research and substantial producer and consumer changes must be our main priority.

ContributorsBrodkin, Emma (Author) / Keahey, Jennifer (Thesis director) / Perkins, Tracy (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Social and Behavioral Sciences (Contributor)
Created2023-05
Description

Animal agriculture is a growing industry worldwide as the global demand for animal products increases. This has resulted in many harmful unintended consequences for human health, the environment, and animal welfare. This paper aims to uncover the hidden costs of negative externalities by answering the question: What types of subsidies

Animal agriculture is a growing industry worldwide as the global demand for animal products increases. This has resulted in many harmful unintended consequences for human health, the environment, and animal welfare. This paper aims to uncover the hidden costs of negative externalities by answering the question: What types of subsidies is the US government distributing to the animal agriculture industry and in what amount? This paper will begin with some background on a few of the externalities created by the animal agriculture industry focusing specifically on environmental issues of water, air, and deforestation. Once this background is established, this will show that animal agriculture is in fact a negative-externality-generating industry. Next, subsidies will be defined and the principal findings of the research will reveal the different forms of support that the US government provides to animal agriculture. Lastly, these subsidies, both direct and indirect, will be quantified.

ContributorsEpel, Erin (Author) / Barca, Lisa (Thesis director) / Rao, Sailesh (Committee member) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of International Letters and Cultures (Contributor)
Created2023-05
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In the Southwestern United States, climate change poses challenges to reliable water access due to droughts, wildfires, and urban development. Arizonan farmers are faced with unpredictable precipitation, muddled legal water rights, and outdated equipment to irrigate their land. Located in Northern Arizona, Verde Valley residents and stakeholders are challenging the

In the Southwestern United States, climate change poses challenges to reliable water access due to droughts, wildfires, and urban development. Arizonan farmers are faced with unpredictable precipitation, muddled legal water rights, and outdated equipment to irrigate their land. Located in Northern Arizona, Verde Valley residents and stakeholders are challenging the way the Verde River water is managed through collaboration, partnerships, and technical changes to water infrastructure. Through interviews conducted with various stakeholders involved in the Verde River ditch irrigation system, ranging from water users to nonprofit organizations, this paper identifies sociotechnical tinkering as an important aspect of maintaining agricultural operations along the river amid political tensions, social relations, and climate change. Through interviews and analysis, this paper further contributes to the relatively new discourse on the concept of sociotechnical tinkering by proving its existence and its subsequent effectiveness in the Verde Valley. Using statements made by respondents, the paper argues that sociotechnical tinkering helps manage resources through political and social relations.

ContributorsNichols, Claire (Author) / Wutich, Amber (Thesis director) / Quimby, Barbara (Committee member) / Barrett, The Honors College (Contributor) / Environmental and Resource Management (Contributor) / School of Sustainability (Contributor) / School of Geographical Sciences and Urban Planning (Contributor)
Created2021-12
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Description
Urban agriculture includes both farming and gardening, typically in a community format, in urban areas. Agrihoods are neighborhoods centered around food production and they are becoming more popular residential areas as the local food movement grows. Agritopia is one of these agrihoods; located in Gilbert, Arizona, it contains both an

Urban agriculture includes both farming and gardening, typically in a community format, in urban areas. Agrihoods are neighborhoods centered around food production and they are becoming more popular residential areas as the local food movement grows. Agritopia is one of these agrihoods; located in Gilbert, Arizona, it contains both an urban farm and a community garden. Agritopia is oft cited for being an exemplary agrihood. This thesis uses Agritopia as a case study for exploring the challenges associated with urban agriculture in the Sonoran Desert.
Most urban agriculture sites experience challenges related to sustainability, but in the Sonoran Desert, even more challenges arise as a result of a unique climate, soil conditions, intense storms, and water scarcity. The objective of this project was to obtain information on common barriers to urban agriculture in the Sonoran Desert, as well as ways to overcome these barriers that will be made public for the purpose of improving sustainability of similar agriculture projects. I used interviews with gardeners and farm staff as my primary research method to gain insight to these barriers and solutions, and I coded their responses relating to challenges according to frequency mentioned. Using my findings, I compiled a thorough list of recommendations that urban agriculture projects in the Sonoran Desert or in similar climatic areas can use to achieve greater success and sustainable outcomes.
ContributorsAnglin, Paige Elizabeth (Author) / Eakin, Hallie (Thesis director) / Norton, Susan (Committee member) / School of Sustainability (Contributor, Contributor) / School of Geographical Sciences and Urban Planning (Contributor) / Barrett, The Honors College (Contributor)
Created2020-05