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Description
Microwave (MW), thermal, and ultraviolet (UV) annealing were used to explore the response of Ag structures on a Ge-Se chalcogenide glass (ChG) thin film as flexible radiation sensors, and Te-Ti chalcogenide thin films as a material for diffusion barriers in microelectronics devices and processing of metallized Cu. Flexible resistive radiation

Microwave (MW), thermal, and ultraviolet (UV) annealing were used to explore the response of Ag structures on a Ge-Se chalcogenide glass (ChG) thin film as flexible radiation sensors, and Te-Ti chalcogenide thin films as a material for diffusion barriers in microelectronics devices and processing of metallized Cu. Flexible resistive radiation sensors consisting of Ag electrodes on a Ge20Se80 ChG thin film and polyethylene naphthalate substrate were exposed to UV radiation. The sensors were mounted on PVC tubes of varying radii to induce bending strains and annealed under ambient conditions up to 150 oC. Initial sensor resistance was measured to be ~1012 Ω; after exposure to UV radiation, the resistance was ~104 Ω. Bending strain and low temperature annealing had no significant effect on the resistance of the sensors. Samples of Cu on Te-Ti thin films were annealed in vacuum for up to 30 minutes and were stable up to 500 oC as revealed using Rutherford backscattering spectrometry (RBS) and four-point-probe analysis. X-ray diffractometry (XRD) indicates Cu grain growth up to 500 oC and phase instability of the Te-Ti barrier at 600 oC. MW processing was performed in a 2.45-GHz microwave cavity on Cu/Te-Ti films for up to 30 seconds to induce oxide growth. Using a calibrated pyrometer above the sample, the temperature of the MW process was measured to be below a maximum of 186 oC. Four-point-probe analysis shows an increase in resistance with an increase in MW time. XRD indicates growth of CuO on the sample surface. RBS suggests oxidation throughout the Te-Ti film. Additional samples were exposed to 907 J/cm2 UV radiation in order to ensure other possible electromagnetically induced mechanisms were not active. There were no changes observed using XRD, RBS or four point probing.
ContributorsRoos, Benjamin, 1990- (Author) / Alford, Terry L. (Thesis advisor) / Theodore, David (Committee member) / Kozicki, Michael (Committee member) / Arizona State University (Publisher)
Created2013
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Description
In the nano-regime many materials exhibit properties that are quite different from their bulk counterparts. These nano-properties have been shown to be useful in a wide range of applications with nanomaterials being used for catalysts, in energy production, as protective coatings, and in medical treatment. While there is no shortage

In the nano-regime many materials exhibit properties that are quite different from their bulk counterparts. These nano-properties have been shown to be useful in a wide range of applications with nanomaterials being used for catalysts, in energy production, as protective coatings, and in medical treatment. While there is no shortage of exciting and novel applications, the world of nanomaterials suffers from a lack of large scale manufacturing techniques. The current methods and equipment used for manufacturing nanomaterials are generally slow, expensive, potentially dangerous, and material specific. The research and widespread use of nanomaterials has undoubtedly been hindered by this lack of appropriate tooling. This work details the effort to create a novel nanomaterial synthesis and deposition platform capable of operating at industrial level rates and reliability.

The tool, referred to as Deppy, deposits material via hypersonic impaction, a two chamber process that takes advantage of compressible fluids operating in the choked flow regime to accelerate particles to up several thousand meters per second before they impact and stick to the substrate. This allows for the energetic separation of the synthesis and deposition processes while still behaving as a continuous flow reactor giving Deppy the unique ability to independently control the particle properties and the deposited film properties. While the ultimate goal is to design a tool capable of producing a broad range of nanomaterial films, this work will showcase Deppy's ability to produce silicon nano-particle films as a proof of concept.

By adjusting parameters in the upstream chamber the particle composition was varied from completely amorphous to highly crystalline as confirmed by Raman spectroscopy. By adjusting parameters in the downstream chamber significant variation of the film's density was achieved. Further it was shown that the system is capable of making these adjustments in each chamber without affecting the operation of the other.
ContributorsFirth, Peter (Author) / Holman, Zachary C (Thesis advisor) / Kozicki, Michael (Committee member) / Goryll, Michael (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Nanomaterials exhibit unique properties that are substantially different from their bulk counterparts. These unique properties have gained recognition and application for various fields and products including sensors, displays, photovoltaics, and energy storage devices. Aerosol Deposition (AD) is a relatively new method for depositing nanomaterials. AD utilizes a nozzle to accelerate

Nanomaterials exhibit unique properties that are substantially different from their bulk counterparts. These unique properties have gained recognition and application for various fields and products including sensors, displays, photovoltaics, and energy storage devices. Aerosol Deposition (AD) is a relatively new method for depositing nanomaterials. AD utilizes a nozzle to accelerate the nanomaterial into a deposition chamber under near-vacuum conditions towards a substrate with which the nanomaterial collides and adheres. Traditional methods for designing nozzles at atmospheric conditions are not well suited for nozzle design for AD methods.

Computational Fluid Dynamics (CFD) software, ANSYS Fluent, is utilized to simulate two-phase flows consisting of a carrier gas (Helium) and silicon nanoparticles. The Cunningham Correction Factor is used to account for non-continuous effects at the relatively low pressures utilized in AD.

The nozzle, referred to herein as a boundary layer compensation (BLC) nozzle, comprises an area-ratio which is larger than traditionally designed nozzles to compensate for the thick boundary layer which forms within the viscosity-affected carrier gas flow. As a result, nanoparticles impact the substrate at velocities up to 300 times faster than the baseline nozzle.
ContributorsHoffman, Trent (Author) / Holman, Zachary C (Thesis advisor) / Herrmann, Marcus (Committee member) / Kozicki, Michael (Committee member) / Arizona State University (Publisher)
Created2017
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Description

This is a test plan document for Team Aegis' capstone project that has the goal of mitigating single event upsets in NAND flash memory caused by space radiation.

ContributorsForman, Oliver Ethan (Co-author) / Smith, Aiden (Co-author) / Salls, Demetra (Co-author) / Kozicki, Michael (Thesis director) / Hodge, Chris (Committee member) / Electrical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description

In collaboration with Moog Broad Reach and Arizona State University, a<br/>team of five undergraduate students designed a hardware design solution for<br/>protecting flash memory data in a spaced-based radioactive environment. Team<br/>Aegis have been working on the research, design, and implementation of a<br/>Verilog- and Python-based error correction code using a Reed-Solomon method<br/>to

In collaboration with Moog Broad Reach and Arizona State University, a<br/>team of five undergraduate students designed a hardware design solution for<br/>protecting flash memory data in a spaced-based radioactive environment. Team<br/>Aegis have been working on the research, design, and implementation of a<br/>Verilog- and Python-based error correction code using a Reed-Solomon method<br/>to identify bit changes of error code. For an additional senior design project, a<br/>Python code was implemented that runs statistical analysis to identify whether<br/>the error correction code is more effective than a triple-redundancy check as well<br/>as determining if the presence of errors can be modeled by a regression model.

ContributorsSalls, Demetra Helen (Author) / Kozicki, Michael (Thesis director) / Hodge, Chris (Committee member) / Electrical Engineering Program (Contributor, Contributor) / School of Mathematical and Statistical Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description
When exposed to radiation, many electronic components become damaged and operate incorrectly. Making sure these components are resistant to radiation effects is especially important for components used in space flight operations. At low dose rates, a phenomenon known as the enhanced low dose rate sensitivity (ELDRS) effect causes an increase

When exposed to radiation, many electronic components become damaged and operate incorrectly. Making sure these components are resistant to radiation effects is especially important for components used in space flight operations. At low dose rates, a phenomenon known as the enhanced low dose rate sensitivity (ELDRS) effect causes an increase in current within linear bipolar circuits. This increase in current is not desirable for space flight operations. Correctly selecting radiation hardened components or figuring out how to deal with the effects for space operation is important, however, radiation testing each component is very expensive and time consuming. To further the future of space travel, a more efficient way of testing is highly desired by the space industry. A low-cost and time-efficient solution is the IMPACT tool. The Multiscale Tool for Modeling Radiation Effects in Linear Bipolar Circuits project aims to improve the existing IMPACT tool for radiation simulation. This tool contains a database of commonly used linear bipolar circuits and allows the user to model the radiation effects. Currently the tool is not very easy to use and the circuit database is limited. The team’s goal and overall outcome of the project is to deliver the IMPACT tool with a user-friendly interface and an expanded circuit database. The team is using multiple tools to improve the overall appearance of the IMPACT tool and running simulations to collect any necessary data for the database expansion. In our thesis, Kerri and Kylie are using LTSpice simulations to expand the database. Cheyenne is using TCAD modeling to create TCAD models of transistors and compare them with her other group member’s simulations.
ContributorsCook, Cheyenne (Author) / Welch, Kerri (Co-author) / Welch, Kylie (Co-author) / Barnaby, Hugh (Thesis director) / Kozicki, Michael (Committee member) / Barrett, The Honors College (Contributor) / Electrical Engineering Program (Contributor)
Created2022-05
Description
The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the

The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the engagement in in-depth interviews with professionals that work in the growing, distribution, and processing of leafy greens. Food safety in the leafy green industry is growing in importance in the wake of costly outbreaks that resulted and recalls and lasting market damage. The Dendritic Identifier provides a unique identification tag that is unclonable, scannable, and compatible with blockchain systems. It is a digital trigger that can be implemented throughout the commercial leafy green supply chain to increase visibility from farm to fork for the consumer and a traceability system for government agencies to trace outbreaks. Efforts like the Food Safety Modernization Act, the Leafy Green Marketing Agreement, and other certifications aim at establishing science-based standards regarding soil testing, water, animal feces, imports, and more. The leafy green supply chains are fragmented in terms of tagging methods and data management services used. There are obstacles in implementing Dendritic Identifiers in that all parties must have systems capable of joining blockchain networks. While there is still a lot to take into consideration for implementation, solutions like the IBM Food Trust pose options for a more fluid transfer of information. Dendritic Identifiers beat out competing tagging technologies in that they work with cellphones, are low cost, and are blockchain compatible. Growers and processors are excited by the opportunity to showcase their extensive food safety measures. The next step in understanding the use environment is to focus on the retail distribution and the retailer specifically.
ContributorsMin, Eleanor (Author) / Manfredo, Mark (Thesis director) / Kozicki, Michael (Committee member) / Barrett, The Honors College (Contributor) / Department of Information Systems (Contributor) / Department of Supply Chain Management (Contributor)
Created2022-05
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Description

The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the

The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the engagement in in-depth interviews with professionals that work in the growing, distribution, and processing of leafy greens. Food safety in the leafy green industry is growing in importance in the wake of costly outbreaks that resulted and recalls and lasting market damage. The Dendritic Identifier provides a unique identification tag that is unclonable, scannable, and compatible with blockchain systems. It is a digital trigger that can be implemented throughout the commercial leafy green supply chain to increase visibility from farm to fork for the consumer and a traceability system for government agencies to trace outbreaks. Efforts like the Food Safety Modernization Act, the Leafy Green Marketing Agreement, and other certifications aim at establishing science-based standards regarding soil testing, water, animal feces, imports, and more. The leafy green supply chains are fragmented in terms of tagging methods and data management services used. There are obstacles in implementing Dendritic Identifiers in that all parties must have systems capable of joining blockchain networks. While there is still a lot to take into consideration for implementation, solutions like the IBM Food Trust pose options for a more fluid transfer of information. Dendritic Identifiers beat out competing tagging technologies in that they work with cellphones, are low cost, and are blockchain compatible. Growers and processors are excited by the opportunity to showcase their extensive food safety measures. The next step in understanding the use environment is to focus on the retail distribution and the retailer specifically.

ContributorsMin, Eleanor (Author) / Manfredo, Mark (Thesis director) / Kozicki, Michael (Committee member) / Barrett, The Honors College (Contributor) / Department of Information Systems (Contributor)
Created2022-05
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Description

The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the

The purpose of this research is to better understand the potential use environment of a Dendritic Identifier within the current leafy green supply chain, including the exploration of potential costs of implementation as well as non-economic costs. This information was collected through an extensive review of literature and through the engagement in in-depth interviews with professionals that work in the growing, distribution, and processing of leafy greens. Food safety in the leafy green industry is growing in importance in the wake of costly outbreaks that resulted and recalls and lasting market damage. The Dendritic Identifier provides a unique identification tag that is unclonable, scannable, and compatible with blockchain systems. It is a digital trigger that can be implemented throughout the commercial leafy green supply chain to increase visibility from farm to fork for the consumer and a traceability system for government agencies to trace outbreaks. Efforts like the Food Safety Modernization Act, the Leafy Green Marketing Agreement, and other certifications aim at establishing science-based standards regarding soil testing, water, animal feces, imports, and more. The leafy green supply chains are fragmented in terms of tagging methods and data management services used. There are obstacles in implementing Dendritic Identifiers in that all parties must have systems capable of joining blockchain networks. While there is still a lot to take into consideration for implementation, solutions like the IBM Food Trust pose options for a more fluid transfer of information. Dendritic Identifiers beat out competing tagging technologies in that they work with cellphones, are low cost, and are blockchain compatible. Growers and processors are excited by the opportunity to showcase their extensive food safety measures. The next step in understanding the use environment is to focus on the retail distribution and the retailer specifically.

ContributorsMin, Eleanor (Author) / Manfredo, Mark (Thesis director) / Kozicki, Michael (Committee member) / Barrett, The Honors College (Contributor) / Department of Information Systems (Contributor)
Created2022-05