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Description
In a laboratory setting, the soil volume change behavior is best represented by using various testing standards on undisturbed or remolded samples. Whenever possible, it is most precise to use undisturbed samples to assess the volume change behavior but in the absence of undisturbed specimens, remodeled samples can be used. If that is the case, the soil is compacted to in-situ density and water content (or matric suction), which should best represent the expansive profile in question. It is standard practice to subject the specimen to a wetting process at a particular net normal stress. Even though currently accepted laboratory testing standard procedures provide insight on how the profile conditions changes with time, these procedures do not assess the long term effects on the soil due to climatic changes. In this experimental study, an assessment and quantification of the effect of multiple wetting/drying cycles on the volume change behavior of two different naturally occurring soils was performed. The changes in wetting and drying cycles were extreme when comparing the swings in matric suction. During the drying cycle, the expansive soil was subjected to extreme conditions, which decreased the moisture content less than the shrinkage limit. Nevertheless, both soils were remolded at five different compacted conditions and loaded to five different net normal stresses. Each sample was subjected to six wetting and drying cycles. During the assessment, it was evident from the results that the swell/collapse strain is highly non-linear at low stress levels. The strain-net normal stress relationship cannot be defined by one single function without transforming the data. Therefore, the dataset needs to be fitted to a bi-modal logarithmic function or to a logarithmic transformation of net normal stress in order to use a third order polynomial fit. It was also determined that the moisture content changes with time are best fit by non-linear functions. For the drying cycle, the radial strain was determined to have a constant rate of change with respect to the axial strain. However, for the wetting cycle, there was not enough radial strain data to develop correlations and therefore, an assumption was made based on 55 different test measurements/observations, for the wetting cycles. In general, it was observed that after each subsequent cycle, higher swelling was exhibited for lower net normal stress values; while higher collapse potential was observed for higher net normal stress values, once the net normal stress was less than/greater than a threshold net normal stress value. Furthermore, the swelling pressure underwent a reduction in all cases. Particularly, the Anthem soil exhibited a reduction in swelling pressure by at least 20 percent after the first wetting/drying cycle; while Colorado soil exhibited a reduction of 50 percent. After about the fourth cycle, the swelling pressure seemed to stabilized to an equilibrium value at which a reduction of 46 percent was observed for the Anthem soil and 68 percent reduction for the Colorado soil. The impact of the initial compacted conditions on heave characteristics was studied. Results indicated that materials compacted at higher densities exhibited greater swell potential. When comparing specimens compacted at the same density but at different moisture content (matric suction), it was observed that specimens compacted at higher suction would exhibit higher swelling potential, when subjected to the same net normal stress. The least amount of swelling strain was observed on specimens compacted at the lowest dry density and the lowest matric suction (higher water content). The results from the laboratory testing were used to develop ultimate heave profiles for both soils. This analysis showed that even though the swell pressure for each soil decreased with cycles, the amount of heave would increase or decrease depending upon the initial compaction condition. When the specimen was compacted at 110% of optimum moisture content and 90% of maximum dry density, it resulted in an ultimate heave reduction of 92 percent for Anthem and 685 percent for Colorado soil. On the other hand, when the soils were compacted at 90% optimum moisture content and 100% of the maximum dry density, Anthem specimens heave 78% more and Colorado specimens heave was reduced by 69%. Based on the results obtained, it is evident that the current methods to estimate heave and swelling pressure do not consider the effect of wetting/drying cycles; and seem to fail capturing the free swell potential of the soil. Recommendations for improvement current methods of practice are provided.
ContributorsRosenbalm, Daniel Curtis (Author) / Zapata, Claudia E (Thesis advisor) / Houston, Sandra L. (Committee member) / Kavazanjian, Edward (Committee member) / Witczak, Mathew W (Committee member) / Arizona State University (Publisher)
Created2013
Description
An eco-industrial park (EIP) is an industrial ecosystem in which a group of co-located firms are involved in collective resource optimization with each other and with the local community through physical exchanges of energy, water, materials, byproducts and services - referenced in the industrial ecology literature as "industrial symbiosis". EIPs, when compared with standard industrial resource sharing networks, prove to be of greater public advantage as they offer improved environmental and economic benefits, and higher operational efficiencies both upstream and downstream in their supply chain.
Although there have been many attempts to adapt EIP methodology to existing industrial sharing networks, most of them have failed for various factors: geographic restrictions by governmental organizations on use of technology, cost of technology, the inability of industries to effectively communicate their upstream and downstream resource usage, and to diminishing natural resources such as water, land and non-renewable energy (NRE) sources for energy production.
This paper presents a feasibility study conducted to evaluate the comparative environmental, economic, and geographic impacts arising from the use of renewable energy (RE) and NRE to power EIPs. Life Cycle Assessment (LCA) methodology, which is used in a variety of sectors to evaluate the environmental merits and demerits of different kinds of products and processes, was employed for comparison between these two energy production methods based on factors such as greenhouse gas emission, acidification potential, eutrophication potential, human toxicity potential, fresh water usage and land usage. To complement the environmental LCA analysis, levelized cost of electricity was used to evaluate the economic impact. This model was analyzed for two different geographic locations; United States and Europe, for 12 different energy production technologies.
The outcome of this study points out the environmental, economic and geographic superiority of one energy source over the other, including the total carbon dioxide equivalent emissions, which can then be related to the total number of carbon credits that can be earned or used to mitigate the overall carbon emission and move closer towards a net zero carbon footprint goal thus making the EIPs truly sustainable.
Although there have been many attempts to adapt EIP methodology to existing industrial sharing networks, most of them have failed for various factors: geographic restrictions by governmental organizations on use of technology, cost of technology, the inability of industries to effectively communicate their upstream and downstream resource usage, and to diminishing natural resources such as water, land and non-renewable energy (NRE) sources for energy production.
This paper presents a feasibility study conducted to evaluate the comparative environmental, economic, and geographic impacts arising from the use of renewable energy (RE) and NRE to power EIPs. Life Cycle Assessment (LCA) methodology, which is used in a variety of sectors to evaluate the environmental merits and demerits of different kinds of products and processes, was employed for comparison between these two energy production methods based on factors such as greenhouse gas emission, acidification potential, eutrophication potential, human toxicity potential, fresh water usage and land usage. To complement the environmental LCA analysis, levelized cost of electricity was used to evaluate the economic impact. This model was analyzed for two different geographic locations; United States and Europe, for 12 different energy production technologies.
The outcome of this study points out the environmental, economic and geographic superiority of one energy source over the other, including the total carbon dioxide equivalent emissions, which can then be related to the total number of carbon credits that can be earned or used to mitigate the overall carbon emission and move closer towards a net zero carbon footprint goal thus making the EIPs truly sustainable.
ContributorsGupta, Vaibhav (Author) / Calhoun, Ronald J (Thesis advisor) / Dooley, Kevin (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2014
Description
As the demand for power increases in populated areas, so will the demand for water. Current power plant technology relies heavily on the Rankine cycle in coal, nuclear and solar thermal power systems which ultimately use condensers to cool the steam in the system. In dry climates, the amount of water to cool off the condenser can be extremely large. Current wet cooling technologies such as cooling towers lose water from evaporation. One alternative to prevent this would be to implement a radiative cooling system. More specifically, a system that utilizes the volumetric radiation emission from water to the night sky could be implemented. This thesis analyzes the validity of a radiative cooling system that uses direct radiant emission to cool water. A brief study on potential infrared transparent cover materials such as polyethylene (PE) and polyvinyl carbonate (PVC) was performed. Also, two different experiments to determine the cooling power from radiation were developed and run. The results showed a minimum cooling power of 33.7 W/m2 for a vacuum insulated glass system and 37.57 W/m2 for a tray system with a maximum of 98.61 Wm-2 at a point when conduction and convection heat fluxes were considered to be zero. The results also showed that PE proved to be the best cover material. The minimum numerical results compared well with other studies performed in the field using similar techniques and materials. The results show that a radiative cooling system for a power plant could be feasible given that the cover material selection is narrowed down, an ample amount of land is available and an economic analysis is performed proving it to be cost competitive with conventional systems.
ContributorsOvermann, William (Author) / Phelan, Patrick (Thesis advisor) / Trimble, Steve (Committee member) / Taylor, Robert (Committee member) / Arizona State University (Publisher)
Created2011
Description
Understanding and predicting climate changes at the urban scale have been an important yet challenging problem in environmental engineering. The lack of reliable long-term observations at the urban scale makes it difficult to even assess past climate changes. Numerical modeling plays an important role in filling the gap of observation and predicting future changes. Numerical studies on the climatic effect of desert urbanization have focused on basic meteorological fields such as temperature and wind. For desert cities, urban expansion can lead to substantial changes in the local production of wind-blown dust, which have implications for air quality and public health. This study expands the existing framework of numerical simulation for desert urbanization to include the computation of dust generation related to urban land-use changes. This is accomplished by connecting a suite of numerical models, including a meso-scale meteorological model, a land-surface model, an urban canopy model, and a turbulence model, to produce the key parameters that control the surface fluxes of wind-blown dust. Those models generate the near-surface turbulence intensity, soil moisture, and land-surface properties, which are used to determine the dust fluxes from a set of laboratory-based empirical formulas. This framework is applied to a series of simulations for the desert city of Erbil across a period of rapid urbanization. The changes in surface dust fluxes associated with urbanization are quantified. An analysis of the model output further reveals the dependence of surface dust fluxes on local meteorological conditions. Future applications of the models to environmental prediction are discussed.
ContributorsTahir, Sherzad Tahseen (Author) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Chen, Kangping (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2019
Description
Many defense, healthcare, and energy applications can benefit from the development of surfaces that easily shed droplets of liquids of interest. Desired wetting properties are typically achieved via altering the surface chemistry or topography or both through surface engineering. Despite many recent advancements, materials modified only on their exterior are still prone to physical degradation and lack durability. In contrast to surface engineering, this thesis focuses on altering the bulk composition and the interior of a material to tune how an exterior surface would interact with liquids. Fundamental and applied aspects of engineering of two material systems with low contact angle hysteresis (i.e. ability to easily shed droplets) are explained. First, water-shedding metal matrix hydrophobic nanoparticle composites with high thermal conductivity for steam condensation rate enhancement are discussed. Despite having static contact angle <90° (not hydrophobic), sustained dropwise steam condensation can be achieved at the exterior surface of the composite due to low contact angle hysteresis (CAH). In order to explain this observation, the effect of varying the length scale of surface wetting heterogeneity over three orders of magnitude on the value of CAH was experimentally investigated. This study revealed that the CAH value is primarily governed by the pinning length which in turn depends on the length scale of wetting heterogeneity. Modifying the heterogeneity size ultimately leads to near isotropic wettability for surfaces with highly anisotropic nanoscale chemical heterogeneities. Next, development of lubricant-swollen polymeric omniphobic protective gear for defense and healthcare applications is described. Specifically, it is shown that the robust and durable protective gear can be made from polymeric material fully saturated with lubricant that can shed all liquids irrespective of their surface tensions even after multiple contact incidences with the foreign objects. Further, a couple of schemes are proposed to improve the rate of lubrication and replenishment of lubricant as well as reduce the total amount of lubricant required in making the polymeric protective gear omniphobic. Overall, this research aims to understand the underlying physics of dynamic surface-liquid interaction and provides simple scalable route to fabricate better materials for condensers and omniphobic protective gear.
ContributorsDamle, Viraj (Author) / Rykaczewski, Konrad (Thesis advisor) / Phelan, Patrick (Committee member) / Lin, Jerry (Committee member) / Herrmann, Marcus (Committee member) / Wang, Robert (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2017