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Description
With the demand growing for more sustainable forms of energy in replacement of fossil fuels, a major obstacle arises in the end-of life solar modules that are disposed of in landfills. Aside from the hazardous materials, silicon solar modules contain valuable and scarce materials such as silver. Silver is used in many industries and many applications therefore the recycling and recovering of it is financially beneficial. The purpose of this research was to achieve high purity and recovery of silver using hydrofluoric acid. The following work presents the feasibility of silver recovery through the process of leaching and electrowinning by examining the percent recovery and cathodic coulombic efficiency, followed by a chemical analysis to determine the purity. Varying conditions in leaching and electrowinning parameters are conducted in a synthetic solution to determine the effect on silver recovery and cathodic coulombic efficiency. It was determined that the silver recovery was dependent on the applied potential, system configuration and time. The system is capable of recovery rates of over 95% at -1 V. The system is further tested on solar cells to prove that silver can be recovered. There was over 99% purity from the experiments conducted in synthetic solution and from solar cells. Additionally, a circular chemistry is proposed that allows the reuse of hydrofluoric acid for leaching and electrowinning.
ContributorsChen, Theresa (Author) / Tao, Meng (Thesis advisor) / Deng, Shuguang (Committee member) / Goryll, Michael (Committee member) / Arizona State University (Publisher)
Created2024
Description
This research will utilize the energy and poverty alleviation framework to investigate a sustainable energy ecosystem for the Wakapoa indigenous community of Guyana. Five questions guide the research – 1) Is there an energy access-development nexus? 2) Can the relationships and trends between key development indicators and electricity access guide policymakers on development activities? 3) Can small-scale concentrated solar and biomass systems provide adequate electrical power to meet the Wakapoa community's domestic and commercial loads economically? 4) What added social value could be generated from the energy system as per Wakapoa context? and 5) What governance systems can be considered to facilitate a sustainable energy ecosystem? In addressing questions 1 and 2, the research collected secondary data on selected countries' key development indexes from the World Bank and Our World in Data. Datasets include the human development index, human capital index, gross domestic product per capita, gross national income per capita, and electricity access. In addressing questions 3 to 5, the research utilized the convergent research design methods, where an inclusive data collection process targeted fifty (50) community residents as survey participants. Statistical analysis of the survey data proved useful in identifying the community needs for the renewable energy system design options utilizing system advisor model (SAM) software, identifying key economic activities that can add social value to the community, and giving key insight into governance practices preferred by the community. Key findings reveal that electricity access exerts a strong and moderate influence on key development indicators, the concentrated solar power and biomass hybrid system can satisfy the electricity demand of the community at the Tier-5 level that can support many traditional and non-traditional economic activities, while key governance support functions such as the community financial aid fund and community management committee can enhance the sustainability of the various operations as well as residents' well-being and livelihood. Future research can address project financing, community productive capacity, and the marketing of goods and services to promote a sustainable energy ecosystem.
ContributorsKanhai, Mahendra N. (Author) / Chhetri, Nalini (Thesis advisor) / Dirks, Gary (Thesis advisor) / Miller, Clark (Committee member) / Stechel, Ellen (Committee member) / Arizona State University (Publisher)
Created2023
Description
Inequities and exclusions, compounded by the increasing intensity of extreme weather events, pose significant challenges to urban planning for low-elevation coastal zones (LECZ). Inclusive development (ID) and urban flood resilience (UFR) have emerged as widely endorsed solutions by scholars. Granting that they gain substantial support and enthusiasm, they have the potential to transform vulnerable urban areas. While their noble intentions are commendable, the intricacies of ID cannot be overlooked, as UFR often inherits and perpetuates the inequalities ingrained in conventional development paradigms. Given the critical importance of ID and UFR in contemporary urban planning, my dissertation research devolved into their fusion by answering my main research question, what constitutes inclusive urban flood resilience? This investigation was carried out through a series of four secondary research questions distributed over three academic papers, each contributing a unique perspective and insights to this burgeoning field. Through a systematic literature review and employing bibliometric and thematic analyses, Chapter 2 offers a comprehensive understanding of inclusive development and a refined definition of the concept. Subsequently, taking Georgetown, the capital city of Guyana, as a case study, Chapter 3 estimates its UFR and employs dimensionality reduction by way of principal component analysis to present these findings in a transparent manner. Chapter 4 builds on the findings of the previous chapters, by first presenting a novel approach to evaluate inclusive development within the framework of the results of Chapter 2, and secondly, together with a systematic meta-analysis of flood resilience measurements, it offers an examination of the ID-UFR nexus. The findings suggest that the concept of inclusive development is nuanced by context-specific definitions, that flood resilience in Georgetown varies among its sub-districts, and that city dimensions (natural, built, social, economic, and institutional), as assessed by pooling global studies, do not share synergistic relationships, being a measure of inclusive development. These findings are critical to urban planning in Georgetown and similar contexts globally as they provide data-driven guidance for understanding these concepts and applying them toward developing inclusive and flood-resilient cities and communities.
ContributorsRenville, Dwayne (Author) / Cheng, Chingwen (Thesis advisor) / Vogel, Kathleen (Thesis advisor) / Chhetri, Netra (Committee member) / Zeng, Ruijie (Committee member) / Arizona State University (Publisher)
Created2023
Description
Public participation is considered an essential process for achieving sustainable urban development. Often, however, insufficient attention is paid to the design of public participation, and processes are formulaic. Then, participation may not match the local context of the communities within which a project is conducted. As a result, participation may become co-optative or coercive, stakeholders may lose trust, and outcomes may favor special interests or be unsustainable, among other shortcomings.
In this research, urban public participation is a collaborative decision-making process between residents, businesses, experts, public officials, and other stakeholders. When processes are not attuned with the local context (participant lifestyles, needs, interests, and capacities) misalignments between process and context arise around living conditions and personal circumstances, stakeholder trust, civic engagement, collaborative capacity, and sustainability literacy, among others.
This dissertation asks (1) what challenges arise when the public participation process does not match the local context, (2) what are key elements of public participation processes that are aligned with the local context, (3) what are ways to design public participation that align with specific local contexts, and (4) what societal qualities and conditions are necessary for meaningful participatory processes?
These questions are answered through four interrelated studies. Study 1 analyzes the current state of the problem by reviewing public participation processes and categorizing common misalignments with the local context. Study 2 envisions a future in which the problem is solved by identifying the features of well-aligned processes. Studies 3 and 4 test interventions for achieving the vision.
This dissertation presents a framework for analyzing the local context in urban development projects and designing public participation processes to meet this context. This work envisions public participation processes aligned with their local context, and it presents directives for designing deliberative decision-making processes for sustainable urban development. The dissertation applies a systems perspective to the social process of public participation, and it provides empirical support for theoretical debates on public participation while creating actionable knowledge for planners and practitioners.
In this research, urban public participation is a collaborative decision-making process between residents, businesses, experts, public officials, and other stakeholders. When processes are not attuned with the local context (participant lifestyles, needs, interests, and capacities) misalignments between process and context arise around living conditions and personal circumstances, stakeholder trust, civic engagement, collaborative capacity, and sustainability literacy, among others.
This dissertation asks (1) what challenges arise when the public participation process does not match the local context, (2) what are key elements of public participation processes that are aligned with the local context, (3) what are ways to design public participation that align with specific local contexts, and (4) what societal qualities and conditions are necessary for meaningful participatory processes?
These questions are answered through four interrelated studies. Study 1 analyzes the current state of the problem by reviewing public participation processes and categorizing common misalignments with the local context. Study 2 envisions a future in which the problem is solved by identifying the features of well-aligned processes. Studies 3 and 4 test interventions for achieving the vision.
This dissertation presents a framework for analyzing the local context in urban development projects and designing public participation processes to meet this context. This work envisions public participation processes aligned with their local context, and it presents directives for designing deliberative decision-making processes for sustainable urban development. The dissertation applies a systems perspective to the social process of public participation, and it provides empirical support for theoretical debates on public participation while creating actionable knowledge for planners and practitioners.
ContributorsCohen, Matthew Charles (Author) / Wiek, Arnim (Thesis advisor) / Manuel-Navarrete, David (Thesis advisor) / Schugurensky, Daniel, 1958- (Committee member) / Arizona State University (Publisher)
Created2015
Description
Despite widespread acknowledgement of the need for transformation towards sustainability, the majority of cities appear stuck in incremental change instead of far-reaching, radical change. While there are numerous obstacles to transformational change, one critical aspect is the process of selecting impactful sustainability programs. The unique and complex nature of sustainability suggests a different approach is needed to program selection than is normal. But, to what extent are cities adapting selection processes in response to sustainability and what effect does this have on sustainable urban transformation? Could there be a more effective process to select programs with greater transformational potential? This dissertation investigates these questions using case studies and action research to add to the general knowledge of urban sustainability program selection and to develop practical knowledge (solutions) for more effective sustainable urban transformation.
The dissertation consists of three studies. Study 1 uses a case study approach to investigate existing sustainability program selection processes in three cities: Avondale, USA; Almere, the Netherlands; and Freiburg, Germany. These cities all express commitment to sustainability but have varying degrees of sustainable development experience, accomplishment, and recognition. Study 2 develops a program selection framework for urban sustainable transformation drawing extensively from the literature on sustainability assessment and related fields, and on participatory input from municipal practitioners in Avondale and Almere. Study 3 assesses the usefulness of the framework in a dual pilot study. Participatory workshops were conducted in which the framework was applied to real-world situations: (i) with the city’s sustainability working group in Avondale; and (ii) with a local energy cooperative in Almere.
Overall, findings suggest cities are not significantly adapting program selection processes in response to the challenges of sustainability. Processes are often haphazard, opportunistic, driven elite actors, and weakly aligned with sustainability principles and goals, which results in selected programs being more incremental than transformational. The proposed framework appears effective at opening up the range of program options considered, stimulating constructive deliberation among participants, and promoting higher order learning. The framework has potential for nudging program selection towards transformational outcomes and more deeply embedding sustainability within institutional culture.
The dissertation consists of three studies. Study 1 uses a case study approach to investigate existing sustainability program selection processes in three cities: Avondale, USA; Almere, the Netherlands; and Freiburg, Germany. These cities all express commitment to sustainability but have varying degrees of sustainable development experience, accomplishment, and recognition. Study 2 develops a program selection framework for urban sustainable transformation drawing extensively from the literature on sustainability assessment and related fields, and on participatory input from municipal practitioners in Avondale and Almere. Study 3 assesses the usefulness of the framework in a dual pilot study. Participatory workshops were conducted in which the framework was applied to real-world situations: (i) with the city’s sustainability working group in Avondale; and (ii) with a local energy cooperative in Almere.
Overall, findings suggest cities are not significantly adapting program selection processes in response to the challenges of sustainability. Processes are often haphazard, opportunistic, driven elite actors, and weakly aligned with sustainability principles and goals, which results in selected programs being more incremental than transformational. The proposed framework appears effective at opening up the range of program options considered, stimulating constructive deliberation among participants, and promoting higher order learning. The framework has potential for nudging program selection towards transformational outcomes and more deeply embedding sustainability within institutional culture.
ContributorsForrest, Nigel (Author) / Wiek, Arnim (Thesis advisor) / Melnick, Rob (Committee member) / Schugurensky, Daniel, 1958- (Committee member) / Arizona State University (Publisher)
Created2015
Description
For most of our history humans have been closely tied to energy provided by the sun. Phases of light and dark initiate major biological functions within each day and regulate patterns of sleep and heightened alertness. Daylight was historically synonymous with sophisticated architecture, providing a mysterious play of light and illuminating productive tasks. It is only within the last 150 years that humans have sought to improve upon daylight, largely replacing it with artificially fueled systems. A new scientific approach to providing interior light has focused on the visible spectrum, negating the remainder of energy from our lives. This thesis considers the full spectrum of natural daylight, and its potential for improving human health, and well being. The literature review explores a brief history of solar architecture leading into the 21st century. A case study of the award winning Arabian Library in Scottsdale Arizona reveals four methods of passive daylight integration. A phenomenological ethnographic methodology assessed the impact of these four strategies on interior lighting quality, documented from the designer's perspective. As the science of photobiology continues to advance, it has become clearly evident that natural daylight provides more than mere illumination, and should be considered an essential element of the interior built environment.
ContributorsMarotta, Nickolas A (Author) / Bernardi, Jose (Thesis advisor) / Rowen, Marthe (Committee member) / Bauer, Kelly (Committee member) / Arizona State University (Publisher)
Created2013
Description
ABSTRACT
Understanding complex and adaptive socio-ecological systems (SES) to deal with our most challenging and overlapping problems such as global climate change, biodiversity loss, and rising consumption rates requires sustainability theory that is commensurate with these problems’ size and complexity. The received United Nations-based sustainability framework aims to achieve a balance among three pillars—economics, environment, and social equity—for today and for future generations. Yet, despite applying this sustainability framework for over a quarter of a century, the Earth is less sustainable, not more. Theoretical trade-offs between environmental conservation and economic growth have often reinforced business-as-usual practices and educational paradigms, and emphasized economic values over ecological limits.
How can the principles of foundational naturalists help clarify, enhance, and advance sustainability discourse? I propose that the principles of Henry David Thoreau (1817-1862), Aldo Leopold (1887-1948), Rachel Carson (1907-1964), and Edward O. Wilson (1927-), express a worldview that captures and integrates a range and depth of historical, normative, economic, ecological, scientific, and social values for a viable and applicable discourse of sustainability.
This analytical study relies on (i.) textual analysis and interpretation of four key naturalists and humanists, (ii.) analysis of secondary sources that illuminate their proto- ecological and sustainability principles, and (iii.) interviews with leading sustainability scholars. Because these thinkers integrate science and ethics, natural history and philosophy, ecology and society, and environmental and economic problems within a holistic worldview, I call them systems naturalists. Their transdisciplinary worldview of one holistic system, with economics subordinated to environmental limits, links important values from the natural sciences and the humanities. The writings and examples of systems naturalists provide more robust historical sustainability principles that can help solve our most challenging SES problems by synthesizing a broad range of knowledge in the sciences, social sciences, and the humanities to inform sustainability paradigm, practices, and pedagogy.
Understanding complex and adaptive socio-ecological systems (SES) to deal with our most challenging and overlapping problems such as global climate change, biodiversity loss, and rising consumption rates requires sustainability theory that is commensurate with these problems’ size and complexity. The received United Nations-based sustainability framework aims to achieve a balance among three pillars—economics, environment, and social equity—for today and for future generations. Yet, despite applying this sustainability framework for over a quarter of a century, the Earth is less sustainable, not more. Theoretical trade-offs between environmental conservation and economic growth have often reinforced business-as-usual practices and educational paradigms, and emphasized economic values over ecological limits.
How can the principles of foundational naturalists help clarify, enhance, and advance sustainability discourse? I propose that the principles of Henry David Thoreau (1817-1862), Aldo Leopold (1887-1948), Rachel Carson (1907-1964), and Edward O. Wilson (1927-), express a worldview that captures and integrates a range and depth of historical, normative, economic, ecological, scientific, and social values for a viable and applicable discourse of sustainability.
This analytical study relies on (i.) textual analysis and interpretation of four key naturalists and humanists, (ii.) analysis of secondary sources that illuminate their proto- ecological and sustainability principles, and (iii.) interviews with leading sustainability scholars. Because these thinkers integrate science and ethics, natural history and philosophy, ecology and society, and environmental and economic problems within a holistic worldview, I call them systems naturalists. Their transdisciplinary worldview of one holistic system, with economics subordinated to environmental limits, links important values from the natural sciences and the humanities. The writings and examples of systems naturalists provide more robust historical sustainability principles that can help solve our most challenging SES problems by synthesizing a broad range of knowledge in the sciences, social sciences, and the humanities to inform sustainability paradigm, practices, and pedagogy.
ContributorsThomas, Craig (Craig F.) (Author) / Minteer, Ben A (Thesis advisor) / Pijawka, David K (Committee member) / Hirt, Paul W (Committee member) / Boone, Christopher (Committee member) / Arizona State University (Publisher)
Created2015
Description
This dissertation explores the intersection of two major developments in global
environmental governance: the vision for a Green Economy and the growing influence of non-state actors. The work draws on multi-sited thick description to analyze how relationships between the state, market, and civil society are being reoriented towards global problems. Its focus is a non-binding agreement between California and Chiapas to create a market in carbon offsets credits for Reducing Emissions for Deforestation and forest Degradation (REDD). The study draws on three bodies of scholarship. From the institutionalist study of global environmental politics, it uses the ideas of orchestration, civil regulation, and private entrepreneurial authority to identity emerging alignments of state and non-state actors, premised on an exchange of public authority and private expertise. From concepts borrowed from science and technology studies, it inquires into the production, certification, and contestation of knowledge. From a constitutionalist perspective, it analyzes how new forms of public law and private expertise are reshaping foundational categories such as territory, authority, and rights. The analysis begins with general research questions applied to California and Chiapas, and the international space where groups influential in these sites are also active: 1) Where are new political and legal institutions emerging, and how are they structured? 2) What role does scientific, legal, and administrative expertise play in shaping these institutions, and vice versa? And 3) How are constitutional elements of the political order being reoriented towards these new spaces and away from the exclusive domain of the nation-state? The dissertation offers a number of propositions for combining institutionalist and constructivist approaches for the study of complex global governing arrangements. It argues that this can help identify constitutional reconfigurations that are not readily apparent using either approach alone.
environmental governance: the vision for a Green Economy and the growing influence of non-state actors. The work draws on multi-sited thick description to analyze how relationships between the state, market, and civil society are being reoriented towards global problems. Its focus is a non-binding agreement between California and Chiapas to create a market in carbon offsets credits for Reducing Emissions for Deforestation and forest Degradation (REDD). The study draws on three bodies of scholarship. From the institutionalist study of global environmental politics, it uses the ideas of orchestration, civil regulation, and private entrepreneurial authority to identity emerging alignments of state and non-state actors, premised on an exchange of public authority and private expertise. From concepts borrowed from science and technology studies, it inquires into the production, certification, and contestation of knowledge. From a constitutionalist perspective, it analyzes how new forms of public law and private expertise are reshaping foundational categories such as territory, authority, and rights. The analysis begins with general research questions applied to California and Chiapas, and the international space where groups influential in these sites are also active: 1) Where are new political and legal institutions emerging, and how are they structured? 2) What role does scientific, legal, and administrative expertise play in shaping these institutions, and vice versa? And 3) How are constitutional elements of the political order being reoriented towards these new spaces and away from the exclusive domain of the nation-state? The dissertation offers a number of propositions for combining institutionalist and constructivist approaches for the study of complex global governing arrangements. It argues that this can help identify constitutional reconfigurations that are not readily apparent using either approach alone.
ContributorsMonfreda, Chad (Author) / Miller, Clark (Thesis advisor) / Hurlbut, James (Committee member) / Abbott, Kenneth (Committee member) / Arizona State University (Publisher)
Created2015
Description
The complexity and interconnectedness of sustainability issues has led to the joining of disciplines. This effort has been primarily within the sciences with minimal attention given to the relationship between science and art. The exclusion of art is problematic since sustainability challenges are not only scientific and technical; they are also cultural, so the arts, as shapers of culture, are critical components that warrant representation. In addition to contributing to the production of culture, arts have also been credited as catalysts for scientific breakthroughs; thus it stands to reason that understanding art-science integration will benefit sustainability’s focus on use-inspired basic research. I focus on placing art and science on equal footing to enhance understanding of how individual artists-scientists and collaborative artist-scientist teams creatively address sustainability challenges. In other words, I address the question “What does it take to develop high functioning artists-scientists or artist-scientist collaborations?”
To answer this question, I used a multipronged approach to triangulate a richer understanding of what art-science synthesis offers sustainability and how it functions. First, I performed an historical analysis of a maladapted wilderness aesthetic and turned to the work Aldo Leopold – an exemplar of an artist-scientist – for a new sustainability aesthetic. Then, I engaged in an individual contemporary art practice, culminating in a gallery exhibit, which displayed ecologically-informed work from a three year study of my backyard. Finally, I conducted small group research of artist-scientist teams tasked with developing interpretive signage for the Tres Rios wetland site. For this final element, I collected survey, wearable sensor, and ethnographic data.
Through this composite research, I found that successful art-science practices require significant energy and time investment. Although art-science is most intensive in an individual practice where the person must become “fluent” in two disciplines, it is still challenging in a group setting where members must become “conversational” in each other’s work. However, successful art-science syntheses appear to result in improved communication skills, better problem articulation, more creative problem solving, and the questioning of personal and disciplinary mental models. Thus, the outcomes of such syntheses warrant the effort required at both the individual and collaborative level.
To answer this question, I used a multipronged approach to triangulate a richer understanding of what art-science synthesis offers sustainability and how it functions. First, I performed an historical analysis of a maladapted wilderness aesthetic and turned to the work Aldo Leopold – an exemplar of an artist-scientist – for a new sustainability aesthetic. Then, I engaged in an individual contemporary art practice, culminating in a gallery exhibit, which displayed ecologically-informed work from a three year study of my backyard. Finally, I conducted small group research of artist-scientist teams tasked with developing interpretive signage for the Tres Rios wetland site. For this final element, I collected survey, wearable sensor, and ethnographic data.
Through this composite research, I found that successful art-science practices require significant energy and time investment. Although art-science is most intensive in an individual practice where the person must become “fluent” in two disciplines, it is still challenging in a group setting where members must become “conversational” in each other’s work. However, successful art-science syntheses appear to result in improved communication skills, better problem articulation, more creative problem solving, and the questioning of personal and disciplinary mental models. Thus, the outcomes of such syntheses warrant the effort required at both the individual and collaborative level.
ContributorsCardenas, Edgar (Author) / Klett, Mark (Thesis advisor) / Minteer, Ben A (Thesis advisor) / Hackett, Edward J (Committee member) / Childers, Dan (Committee member) / Arizona State University (Publisher)
Created2015
Description
Vegetative filter strips (VFS) are an effective methodology used for storm water management particularly for large urban parking lots. An optimization model for the design of vegetative filter strips that minimizes the amount of land required for stormwater management using the VFS is developed in this study. The resulting optimization model is based upon the kinematic wave equation for overland sheet flow along with equations defining the cumulative infiltration and infiltration rate.
In addition to the stormwater management function, Vegetative filter strips (VFS) are effective mechanisms for control of sediment flow and soil erosion from agricultural and urban lands. Erosion is a major problem associated with areas subjected to high runoffs or steep slopes across the globe. In order to effect economy in the design of grass filter strips as a mechanism for sediment control & stormwater management, an optimization model is required that minimizes the land requirements for the VFS. The optimization model presented in this study includes an intricate system of equations including the equations defining the sheet flow on the paved and grassed area combined with the equations defining the sediment transport over the vegetative filter strip using a non-linear programming optimization model. In this study, the optimization model has been applied using a sensitivity analysis of parameters such as different soil types, rainfall characteristics etc., performed to validate the model
In addition to the stormwater management function, Vegetative filter strips (VFS) are effective mechanisms for control of sediment flow and soil erosion from agricultural and urban lands. Erosion is a major problem associated with areas subjected to high runoffs or steep slopes across the globe. In order to effect economy in the design of grass filter strips as a mechanism for sediment control & stormwater management, an optimization model is required that minimizes the land requirements for the VFS. The optimization model presented in this study includes an intricate system of equations including the equations defining the sheet flow on the paved and grassed area combined with the equations defining the sediment transport over the vegetative filter strip using a non-linear programming optimization model. In this study, the optimization model has been applied using a sensitivity analysis of parameters such as different soil types, rainfall characteristics etc., performed to validate the model
ContributorsKhatavkar, Puneet N (Author) / Mays, Larry W. (Thesis advisor) / Fox, Peter (Committee member) / Wang, Zhihua (Committee member) / Mascaro, Giuseppe (Committee member) / Arizona State University (Publisher)
Created2015