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- All Subjects: mantle
- Creators: Hervig, Richard
This study presents a total of 113 individual analyses of H2O contents and hydrogen isotopic compositions of NAPs in the shergottites Zagami, Los Angeles, QUE 94201, SaU 005, and Tissint, and the nakhlites Nakhla, Lafayette, and Yamato 000593. The hydrogen isotopic variation between and within meteorites may be due to one or more processes including: interaction with the martian atmosphere, magmatic degassing, subsolidus alteration (including shock), and/or terrestrial contamination. Taking into consideration the effects of these processes, the hydrogen isotope composition of the martian mantle may be similar to that of the Earth. Additionally, this study calculated upper limits on the H2O contents of the shergottite and nakhlite parent melts based on the measured minimum H2O abundances in their maskelynites and pyroxenes, respectively. These calculations, along with some petrogenetic assumptions based on previous studies, were subsequently used to infer the H2O contents of the mantle source reservoirs of the depleted shergottites (200-700 ppm) and the nakhlites (10-100 ppm). This suggests that mantle source of the nakhlites is systematically drier than that of the depleted shergottites, and the upper mantle of Mars may have preserved significant heterogeneity in its H2O content. Additionally, this range of H2O contents is not dissimilar to the range observed for the Earth’s upper mantle.
Although nitrogen is the dominant element in Earth’s atmosphere, it is depleted in the bulk silicate Earth (relative to expected volatile abundances established by carbonaceous chondrites). To resolve this inconsistency, it has been hypothesized that this “missing nitrogen” may actually be stored within the Earth’s deep interior. In this work, we use multi-anvil press experiments to synthesize solid solution mixtures of the mantle transition zone mineral wadsleyite (Mg2SiO4) and silicon nitride (Si3N4). Successful synthesis of a 90% Si3N4, 10% Mg2SiO4 solid solution implies that nitrogen may not be sequestered within the most abundant mineral phases in the Earth’s mantle. Instead, nitrogen-rich accessory phases may hold the key to studying nitrogen storage within the deep interior. Ultimately, quantifying the amount of nitrogen within the mantle will further our understanding of the N cycle, which is vital to maintaining planetary habitability. Similar N cycling processes may be occurring on other rocky bodies; therefore, studying nitrogen storage may be an important part of determining habitability conditions on other worlds, both within in our solar system and beyond.