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157734 https://hdl.handle.net/2286/R.I.54982 http://rightsstatements.org/vocab/InC/1.0/ 2019 127 pages Doctoral Dissertation Academic theses Text eng Gharib-Nezhad, Ehsan Line, Michael R. Lyons, James R. Sayres, Scott G. Heyden, Bjorn Matthias Arizona State University Doctoral Dissertation Chemistry 2019 One strategic objective of the National Aeronautics and Space Administration (NASA) is to find life on distant worlds. Current and future missions either space telescopes or Earth-based observatories are frequently used to collect information through the detection of photons from exoplanet atmospheres. The primary challenge is to fully understand the nature of these exo-atmospheres. To this end, atmospheric modeling and sophisticated data analysis techniques are playing a key role in understanding the emission and transmission spectra of exoplanet atmospheres. Of critical importance to the interpretation of such data are the opacities (or absorption cross-sections) of key molecules and atoms. During my Doctor of Philosophy years, the central focus of my projects was assessing and leveraging these opacity data. I executed this task with three separate projects: 1) laboratory spectroscopic measurement of the infrared spectra of CH4 in H2 perturbing gas in order to extract pressure-broadening and pressure-shifts that are required to accurately model the chemical composition of exoplanet atmospheres; 2) computing the H2O opacity data using ab initio line list for pressure and temperature ranges of 10^-6–300 bar and 400–1500 K, and then utilizing these H2O data in radiative transfer models to generate transmission and emission exoplanetary spectra; and 3) assessing the impact of line positions in different H2O opacities on the interpretation of ground-based observational exoplanetary data through the cross-correlation technique. Atmospheric chemistry Astrophysics Physical Chemistry Exoplanets (Extrasolar planets) Infrared spectroscopy Methane (CH4) Opacity (Absorption Cross-Sections) Pressure-broadening Water (H2O) Assessing the Impact of H2O and CH4 Opacity Data in Exoplanetary Atmospheres: Laboratory Measurements and Radiative Transfer Modeling Approaches