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154799 https://hdl.handle.net/2286/R.I.39444 http://rightsstatements.org/vocab/InC/1.0/ All Rights Reserved 2016 viii, 53 pages : illustrations (some color) Masters Thesis Academic theses Text eng Williams, Suzanne Jean Lin, Jerry Y.S. Emady, Heather Mu, Bin Arizona State University Partial requirement for: M.S., Arizona State University, 2016 Includes bibliographical references (pages 44-46) Field of study: Chemical engineering While the solution diffusion model and pore flow model dominate pervaporation transport mechanism modeling, a new model combining the solution diffusion and viscous flow models is validated using membranes with large scale defects exceeding 2 nm in diameter. A range of membranes was characterized using scanning electron microscopy and x-ray diffraction (XRD) to determine quality and phase characteristics. MFI zeolite membranes of He/SF6 pure gas permeation ideal selectivities of 25, 15, and 3 for good, medium, and poor quality membranes were subjected to liquid pervaporations with a 5% ethanol in water feed, by weight. Feed pressure was increased from 1 to 5 atm, to validate existence of viscous flow in the defects. Component molar flux is modeled using the solution diffusion model and the viscous flow model, via J_i=F_i (γ_i x_i P_i^sat )+(ρ )/M_W ∅/μ_ij x_i P_h. A negative coefficient of thermal expansion is observed as permeances drop as a function of temperature in all three membranes, where ϕ=((ϵr_p^2)/τ∆x). Experimental parameter ϕ increased as a function of temperature, and increased with decreasing membrane quality. This further proves that zeolitic pores are shrinking in one direction, and pulling intercrystalline voids larger, increasing the (ϵ/τ) ratio. Permiabilities of the bad, medium, and good quality membrane also decreased over time for both ethanol and water, meaning that fundamental membrane characteristics changed as a function of temperature. To conclude, the model reasonably fits empirical data reasonably well. Chemical Engineering pervaporation Zeolites Ethanol Membranes (Technology) Experimental and modeling study on pervaporation separation of ethanol and water mixture by polycrystalline MFI zeolite membranes