The Resource Description Framework (RDF) is a specification that aims to support the conceptual modeling of metadata or information about resources in the form of a directed graph composed of triples of knowledge (facts). RDF also provides mechanisms to encode meta-information (such as source, trust, and certainty) about facts already existing in a knowledge base through a process called reification. In this thesis, an extension to the current RDF specification is proposed in order to enhance RDF triples with an application specific weight (cost). Unlike reification, this extension treats these additional weights as first class knowledge attributes in the RDF model, which can be leveraged by the underlying query engine. Additionally, current RDF query languages, such as SPARQL, have a limited expressive power which limits the capabilities of applications that use them. Plus, even in the presence of language extensions, current RDF stores could not provide methods and tools to process extended queries in an efficient and effective way. To overcome these limitations, a set of novel primitives for the SPARQL language is proposed to express Top-k queries using traditional query patterns as well as novel predicates inspired by those from the XPath language. Plus, an extended query processor engine is developed to support efficient ranked path search, join, and indexing. In addition, several query optimization strategies are proposed, which employ heuristics, advanced indexing tools, and two graph metrics: proximity and sub-result inter-arrival time. These strategies aim to find join orders that reduce the total query execution time while avoiding worst-case pattern combinations. Finally, extensive experimental evaluation shows that using these two metrics in query optimization has a significant impact on the performance and efficiency of Top-k queries. Further experiments also show that proximity and inter-arrival have an even greater, although sometimes undesirable, impact when combined through aggregation functions. Based on these results, a hybrid algorithm is proposed which acknowledges that proximity is more important than inter-arrival time, due to its more complete nature, and performs a fine-grained combination of both metrics by analyzing the differences between their individual scores and performing the aggregation only if these differences are negligible.