Description

Formally zerovalent (κ[superscript 3]-phosphine)Fe(η[superscript 4]-COT) complexes supported by either Triphos (PhP(CH[subscript 2]CH[subscript 2]PPh[subscript 2])[subscript 2]) or Triphos* (H[subscript 3]CC(CH[subscript 2]PPh[subscript 2])[subscript 3]) have been prepared following chelate addition to (COT)[subscript

Formally zerovalent (κ[superscript 3]-phosphine)Fe(η[superscript 4]-COT) complexes supported by either Triphos (PhP(CH[subscript 2]CH[subscript 2]PPh[subscript 2])[subscript 2]) or Triphos* (H[subscript 3]CC(CH[subscript 2]PPh[subscript 2])[subscript 3]) have been prepared following chelate addition to (COT)[subscript 2]Fe (COT = 1,3,5,7-cyclooctatetraene) and by reduction of the respective dibromide complexes in the presence of excess COT.

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Date Created
  • 2014-12-22
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  • Text
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    Identifier
    • Digital object identifier: 10.1021/om500909h
    • Identifier Type
      International standard serial number
      Identifier Value
      0276-7333
    • Identifier Type
      International standard serial number
      Identifier Value
      1520-6041
    Note
    • This document is the Accepted Manuscript version of a Published Work that appeared in final form in ORGANOMETALLICS, copyright American Chemical Society, after peer review and technical editing by the publisher. To access the final published work, see http://dx.doi.org/10.1021/om500909h, opens in a new window

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    Mukhopadhyay, Tufan K., Flores, Marco, Feller, Russell K., Scott, Brian L., Taylor, R. Dean, Paz-Pasternak, Moshe, Henson, Neil J., Rein, Francisca N., Smythe, Nathan C., Trovitch, Ryan J., & Gordon, John C. (2014). A New Spin on Cyclooctatetraene (COT) Redox Activity: Low-Spin Iron(1) Complexes That Exhibit Antiferromagnetic Coupling to a Singly Reduced eta(4)-COT Ligand. ORGANOMETALLICS, 33(24), 7101-7112. http://dx.doi.org/10.1021/om500909h

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