Description

Singly deuterated silylene has been detected and characterized in the gas-phase using high-resolution, two-dimensional, optical spectroscopy. Rotationally resolved lines in the 0[0 over 0][˜ over X][superscript 1]A′ → [˜ over

Singly deuterated silylene has been detected and characterized in the gas-phase using high-resolution, two-dimensional, optical spectroscopy. Rotationally resolved lines in the 0[0 over 0][˜ over X][superscript 1]A′ → [˜ over A][superscript 1]A′′000X˜1A′→A˜1A″ band are assigned to both c-type perpendicular transition and additional parallel, axis-switching induced bands.

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Date Created
  • 2016-06-27
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  • Text
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    Identifier
    • Digital object identifier: 10.1063/1.4954702
    • Identifier Type
      International standard serial number
      Identifier Value
      1833-3672
    • Identifier Type
      International standard serial number
      Identifier Value
      1839-3527
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    Kokkin, D. L., Ma, T., Steimle, T., & Sears, T. J. (2016). Detection and characterization of singly deuterated silylene, SiHD, via optical spectroscopy. The Journal of Chemical Physics, 144(24), 244304. doi:10.1063/1.4954702

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